Significantly Dense Two-Dimensional Hydrogen-Bond Network in a Layered Zirconium Phosphate Leading to High Proton Conductivities in Both Water-Assisted Low-Temperature and Anhydrous Intermediate-Temperature Regions.

Title Significantly Dense Two-Dimensional Hydrogen-Bond Network in a Layered Zirconium Phosphate Leading to High Proton Conductivities in Both Water-Assisted Low-Temperature and Anhydrous Intermediate-Temperature Regions.
Authors D. Gui; T. Zheng; J. Xie; Y. Cai; Y. Wang; L. Chen; J. Diwu; Z. Chai; S. Wang
Journal Inorg Chem
DOI 10.1021/acs.inorgchem.6b02308
Abstract

A highly stable layered zirconium phosphate, (NH4)2[ZrF2(HPO4)2] (ZrP-1), was synthesized by an ionothermal method and contains an extremely dense two-dimensional hydrogen-bond network that is thermally stable up to 573 K, leading to combined ultrahigh water-assisted proton conductivities of 1.45 × 10(-2) S cm(-1) at 363 K/95% relative humidity and sustainable anhydrous proton conductivity of 1.1 × 10(-5) S cm(-1) at 503 K.

Citation D. Gui; T. Zheng; J. Xie; Y. Cai; Y. Wang; L. Chen; J. Diwu; Z. Chai; S. Wang.Significantly Dense Two-Dimensional Hydrogen-Bond Network in a Layered Zirconium Phosphate Leading to High Proton Conductivities in Both Water-Assisted Low-Temperature and Anhydrous Intermediate-Temperature Regions.. Inorg Chem. 2016;55(24):1250812511. doi:10.1021/acs.inorgchem.6b02308

Related Elements

Zirconium

See more Zirconium products. Zirconium (atomic symbol: Zr, atomic number: 40) is a Block D, Group 4, Period 5 element with an atomic weight of 91.224. Zirconium Bohr ModelThe number of electrons in each of Zirconium's shells is 2, 8, 18, 10, 2 and its electron configuration is [Kr]4d2 5s2. The zirconium atom has a radius of 160 pm and a Van der Waals radius of 186 pm. Zirconium was discovered by Martin Heinrich Klaproth in 1789 and first isolated by Jöns Jakob Berzelius in 1824. In its elemental form, zirconium has a silvery white appearance that is similar to titanium. Zirconium's principal mineral is zircon (zirconium silicate). Elemental ZirconiumZirconium is commercially produced as a byproduct of titanium and tin mining and has many applications as a opacifier and a refractory material. It is not found in nature as a free element. The name of zirconium comes from the mineral zircon, the most important source of zirconium, and from the Persian wordzargun, meaning gold-like.

Phosphorus

Phosphorus Bohr ModelSee more Phosphorus products. Phosphorus (atomic symbol: P, atomic number: 15) is a Block P, Group 15, Period 3 element. The number of electrons in each of Phosphorus's shells is 2, 8, 5 and its electronic configuration is [Ne] 3s2 3p3. The phosphorus atom has a radius of 110.5.pm and its Van der Waals radius is 180.pm. Phosphorus is a highly-reactive non-metallic element (sometimes considered a metalloid) with two primary allotropes, white phosphorus and red phosphorus its black flaky appearance is similar to graphitic carbon. Compound forms of phosphorus include phosphates and phosphides. Phosphorous was first recognized as an element by Hennig Brand in 1669 its name (phosphorus mirabilis, or "bearer of light") was inspired from the brilliant glow emitted by its distillation.

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