Slow magnetic relaxation in luminescent mononuclear dysprosium(iii) and erbium(iii) pentanitrate complexes with the same LnO10 coordination geometry.

Title Slow magnetic relaxation in luminescent mononuclear dysprosium(iii) and erbium(iii) pentanitrate complexes with the same LnO10 coordination geometry.
Authors L. Chen; J.J. Zhou; A. Yuan; Y. Song
Journal Dalton Trans
DOI 10.1039/c7dt02905e
Abstract

Two isostructural mononuclear Dy and Er pentanitrate complexes with an LnO10 coordination geometry have been synthesized and studied by single-crystal X-ray diffraction, luminescence and magnetic measurements. Slow relaxation of the magnetization behavior is simultaneously observed in two complexes with the same coordination environment, despite the different types of the 4f-shell electron distribution. Meanwhile, both complexes exhibit the respective characteristic Ln(iii) photoluminescence.

Citation L. Chen; J.J. Zhou; A. Yuan; Y. Song.Slow magnetic relaxation in luminescent mononuclear dysprosium(iii) and erbium(iii) pentanitrate complexes with the same LnO10 coordination geometry.. Dalton Trans. 2017;46(45):1581215818. doi:10.1039/c7dt02905e

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Erbium

See more Erbium products. Erbium (atomic symbol: Er, atomic number: 68) is a Block F, Group 3, Period 6 element with an atomic radius of 167.259. Erbium Bohr ModelThe number of electrons in each of Erbium's shells is [2, 8, 18, 30, 8, 2] and its electron configuration is [Xe]4f12 6s2. The erbium atom has a radius of 176 pm and a Van der Waals radius of 235 pm. Erbium was discovered by Carl Mosander in 1843. Sources of Erbium include the mineral monazite and sand ores. Erbium is a member of the lanthanide or rare earth series of elements.Elemental Erbium Picture In its elemental form, erbium is soft and malleable. It is fairly stable in air and does not oxidize as rapidly as some of the other rare earth metals. Erbium's ions fluoresce in a bright pink color, making them highly useful for imaging and optical applications. It is named after the Swedish town Ytterby where it was first discovered.

Dysprosium

See more Dysprosium products. Dysprosium (atomic symbol: Dy, atomic number: 66) is a Block F, Group 3, Period 6 element with an atomic radius of 162.5. Dysprosium Bohr ModelThe number of electrons in each of dysprosium's shells is [2, 8, 18, 28, 8, 2] and its electron configuration is [Xe]4f10 6s2. The dysprosium atom has an atomic radius of 178 pm and a Van der Waals radius of 229 pm. Dysprosium was first discovered by Paul Emile Lecoq de Boisbaudran in 1886. In its elemental form, dysprosium has a silvery-white appearance. Elemental Dysprosium PictureIt is a member of the lanthanide or rare earth series of elements and, along with holmium, has the highest magnetic strength of all other elements on the periodic table, especially at low temperatures. Dysprosium is found in various minerals including bastnäsite, blomstrandine, euxenite, fergusonite, gadolinite, monazite, polycrase and xenotime. It is not found in nature as a free element. The element name originates from the Greek word dysprositos, meaning hard to get at.

Nitrogen

See more Nitrogen products. Nitrogen is a Block P, Group 15, Period 2 element. Its electron configuration is [He]2s22p3. Nitrogen is an odorless, tasteless, colorless and mostly inert gas. It is the seventh most abundant element in the universe and it constitutes 78.09% (by volume) of Earth's atmosphere. Nitrogen was discovered by Daniel Rutherford in 1772.

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