Sonochemical synthesis and characterization of new seven coordinated zinc, cadmium and mercury nitrate complexes: New precursors for nanostructure metal oxides.

Title Sonochemical synthesis and characterization of new seven coordinated zinc, cadmium and mercury nitrate complexes: New precursors for nanostructure metal oxides.
Authors M. Jahromi; M. Montazerozohori; A. Masoudiasl; E. Houshyar; S. Joohari; J.M. White
Journal Ultrason Sonochem
DOI 10.1016/j.ultsonch.2017.10.025
Abstract

The nitrate complexes of group 12 elements with a tridentate Schiff base ligand (L?=?(E)-N1-((E)-3- phenylallylidene)-N2-(2-((E)-((E)-3-phenylallylidene) amino)ethyl) ethane-1,2-diamine) were synthesized via sonochemical process and characterized by various physical and chemical methods. The structural analysis of the zinc nitrate complex by single crystal X-ray diffraction analysis shows that the central atom is seven-coordinated by three nitrogen atoms from the Schiff base ligand as well as four oxygen atoms from two different nitrate anions. The geometry around the metal center can be described as a distorted pentagonal bipyramid. The crystal packing analysis of zinc nitrate complex indicates that the intermolecular interactions related to nitrate groups plays the essential role in the orientation of supramolecular structure. Hirshfeld surfaces (HS) and their corresponding fingerprint plots (FP) have been also used for further investigation of crystal structure of zinc nitrate complex. Furthermore thermal analyses (TG/DTG) of three nanostructure complexes were carried out and discussed. Finally, direct thermolysis of zinc and cadmium nitrate complexes in air atmosphere led to the production of zinc and cadmium oxide nanoparticles.

Citation M. Jahromi; M. Montazerozohori; A. Masoudiasl; E. Houshyar; S. Joohari; J.M. White.Sonochemical synthesis and characterization of new seven coordinated zinc, cadmium and mercury nitrate complexes: New precursors for nanostructure metal oxides.. Ultrason Sonochem. 2018;41:590599. doi:10.1016/j.ultsonch.2017.10.025

Related Elements

Mercury

Mercury Bohr ModelSee more Mercury products. Mercury (atomic symbol: Hg, atomic number: 80) is a Block D, Group 12, Period 6 element with an atomic weight of 200.59. The number of electrons in each of mercury's shells is 2, 8, 18,32, 18, 2 and its electron configuration is [Xe] 4f14 5d10 6s2. The mercury atom has a radius of 151 pm and a Van der Waals radius of 209 pm. It is named after the planet Mercury and often referred to as "quicksilver" due to its appearance as a silvery liquid. Mercury has low melting and boiling points. It is a poor conductor of heat, but a fair conductor of electricity. Mercury is found both as a free element and in cinnabar, corderoite, and livingstonite ores.

Zinc

See more Zinc products. Zinc (atomic symbol: Zn, atomic number: 30) is a Block D, Group 12, Period 4 element with an atomic weight of 65.38. The number of electrons in each of zinc's shells is 2, 8, 18, 2, and its electron configuration is [Ar] 3d10 4s2. Zinc Bohr ModelThe zinc atom has a radius of 134 pm and a Van der Waals radius of 210 pm. Zinc was discovered by Indian metallurgists prior to 1000 BC and first recognized as a unique element by Rasaratna Samuccaya in 800. Zinc was first isolated by Andreas Marggraf in 1746. In its elemental form, zinc has a silver-gray appearance. It is brittle at ordinary temperatures but malleable at 100 °C to 150 °C.Elemental Zinc It is a fair conductor of electricity, and burns in air at high red producing white clouds of the oxide. Zinc is mined from sulfidic ore deposits. It is the 24th most abundant element in the earth's crust and the fourth most common metal in use (after iron, aluminum, and copper). The name zinc originates from the German word "zin," meaning tin.

Cadmium

See more Cadmium products. Cadmium (atomic symbol: Cd, atomic number: 48) is a Block D, Group 12, Period 5 element with an atomic weight of 112.411. Cadmium Bohr ModelThe number of electrons in each of Cadmium's shells is 2, 8, 18, 18, 2 and its electron configuration is [Kr]4d10 5s2. The cadmium atom has a radius of 151 pm and a Van der Waals radius of 230 pm. Cadmium was discovered and first isolated by Karl Samuel Leberecht Hermann and Friedrich Stromeyer in 1817. In its elemental form, cadmium has a silvery bluish gray metallic appearance. Cadmium makes up about 0.1 ppm of the earth's crust. Elemental CadmiumNo significant deposits of cadmium containing ores are known, however, it is sometimes found in its metallic form. It is a common impurity in zinc ores and is isolated during the production of zinc. Cadmium is a key component in battery production and particular pigments and coatings due to its distinct yellow color. Cadmium oxide is used in phosphors for television picture tubes. The name Cadmium originates from the Latin word 'cadmia' and the Greek word 'kadmeia'.

Nitrogen

See more Nitrogen products. Nitrogen is a Block P, Group 15, Period 2 element. Its electron configuration is [He]2s22p3. Nitrogen is an odorless, tasteless, colorless and mostly inert gas. It is the seventh most abundant element in the universe and it constitutes 78.09% (by volume) of Earth's atmosphere. Nitrogen was discovered by Daniel Rutherford in 1772.

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