Sonochemical synthesis of amide-functionalized metal-organic framework/graphene oxide nanocomposite for the adsorption of methylene blue from aqueous solution.

Title Sonochemical synthesis of amide-functionalized metal-organic framework/graphene oxide nanocomposite for the adsorption of methylene blue from aqueous solution.
Authors M. Tanhaei; A.Reza Mahjoub; V. Safarifard
Journal Ultrason Sonochem
DOI 10.1016/j.ultsonch.2017.09.030
Abstract

Graphene oxide-[Zn2(oba)2(bpfb)]·(DMF)5 metal-organic framework nanocomposite (GO-TMU-23; H2oba=4,4'-oxybisbenzoic acid, bpfb=N,N'-bis-(4-pyridylformamide)-1,4-benzenediamine, DMF=N,N-dimethylformamide) is prepared through a simple and large-scale sonochemical preparation method at room temperature. The obtained nanocomposite is characterized by Field Emission Scanning Electron Microscopy (FE-SEM), powder X-ray diffraction (PXRD) and FT-IR spectroscopy. Additionally, the absorption ability of GO-TMU-23 nanocomposite toward cationic dye methylene blue was also performed. Significantly, GO-TMU-23 nanocomposite exhibits remarkably accelerated adsorption kinetics for methylene blue in comparison with the parent materials. The adsorption process shows that 90% of the dye has been removed and the equilibrium status has been reached in 2min by using the nanocomposites as the adsorbent.

Citation M. Tanhaei; A.Reza Mahjoub; V. Safarifard.Sonochemical synthesis of amide-functionalized metal-organic framework/graphene oxide nanocomposite for the adsorption of methylene blue from aqueous solution.. Ultrason Sonochem. 2018;41:189195. doi:10.1016/j.ultsonch.2017.09.030

Related Elements

Carbon

See more Carbon products. Carbon (atomic symbol: C, atomic number: 6) is a Block P, Group 14, Period 2 element. Carbon Bohr ModelThe number of electrons in each of Carbon's shells is 2, 4 and its electron configuration is [He]2s2 2p2. In its elemental form, carbon can take various physical forms (known as allotropes) based on the type of bonds between carbon atoms; the most well known allotropes are diamond, graphite, amorphous carbon, glassy carbon, and nanostructured forms such as carbon nanotubes, fullerenes, and nanofibers . Carbon is at the same time one of the softest (as graphite) and hardest (as diamond) materials found in nature. It is the 15th most abundant element in the Earth's crust, and the fourth most abundant element (by mass) in the universe after hydrogen, helium, and oxygen. Carbon was discovered by the Egyptians and Sumerians circa 3750 BC. It was first recognized as an element by Antoine Lavoisier in 1789.

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