The High Resolution 4f-5d Absorption Spectrum of Divalent Dysprosium (Dy2+) in Strontium Chloride Host SrCl2 - Fine Structure and Zero-phonon Transitions Revealed.

Title The High Resolution 4f-5d Absorption Spectrum of Divalent Dysprosium (Dy2+) in Strontium Chloride Host SrCl2 - Fine Structure and Zero-phonon Transitions Revealed.
Authors M. Karbowiak; C. Rudowicz; J. Cichos
Journal J Phys Chem A
DOI 10.1021/acs.jpca.7b08620
Abstract

The virtual lack of information on electronic spectra of divalent lanthanide elements (Ln2+) other than Sm2+, Eu2+, Tm2+ and Yb2+ has prompted us to set for synthesis and characterization of novel Ln2+ systems. First successful attempt concerned SrCl2:Nd2+ single crystals. Here, we report stabilization of divalent dysprosium in a chloride host. Importantly this has been accomplished with Dy ions introduced in a divalent state during synthesis, unlike by ?-irradiation of Dy3+ systems employed previously. This synthesis method yields good quality SrCl2:Dy2+ single crystals. The electronic absorption spectra of Dy2+ doped in SrCl2 have been recorded with high resolution at liquid helium temperature (4.2 K). Identification of the absorption bands occurring in the spectral range of 5000 - 45000 cm-1 is achieved. Based on theoretical calculations using semi-empirical Hamiltonian model, assignment of bands and determination of the Hamiltonian parameters for Dy2+(4f95d1) configuration is carried out. The experimental and theoretical studies reveal fine structure and zero-phonon transitions and thus enable high resolution assignment of spectral lines. It is shown that spin-forbidden transitions gain relatively high intensity due to significant admixing of low-spin character to nominally high-spin states.

Citation M. Karbowiak; C. Rudowicz; J. Cichos.The High Resolution 4f-5d Absorption Spectrum of Divalent Dysprosium (Dy2+) in Strontium Chloride Host SrCl2 - Fine Structure and Zero-phonon Transitions Revealed.. J Phys Chem A. 2018. doi:10.1021/acs.jpca.7b08620

Related Elements

Dysprosium

See more Dysprosium products. Dysprosium (atomic symbol: Dy, atomic number: 66) is a Block F, Group 3, Period 6 element with an atomic radius of 162.5. Dysprosium Bohr ModelThe number of electrons in each of dysprosium's shells is [2, 8, 18, 28, 8, 2] and its electron configuration is [Xe]4f10 6s2. The dysprosium atom has an atomic radius of 178 pm and a Van der Waals radius of 229 pm. Dysprosium was first discovered by Paul Emile Lecoq de Boisbaudran in 1886. In its elemental form, dysprosium has a silvery-white appearance. Elemental Dysprosium PictureIt is a member of the lanthanide or rare earth series of elements and, along with holmium, has the highest magnetic strength of all other elements on the periodic table, especially at low temperatures. Dysprosium is found in various minerals including bastnäsite, blomstrandine, euxenite, fergusonite, gadolinite, monazite, polycrase and xenotime. It is not found in nature as a free element. The element name originates from the Greek word dysprositos, meaning hard to get at.

Chlorine

Chlorine is a Block P, Group 17, Period 3 element. Its electron configuration is [Ne]3s23p5. The chlorine atom has a covalent radius of 102±4 pm and its Van der Waals radius is 175 pm. Chlorine ModelIn its elemental form, chlorine is a yellow-green gas. Chlorine is the second lightest halogen after fluorine. It has the third highest electronegativity and the highest electron affinity of all elements, making it a strong oxidizing agent. It is rarely found by itself in nature. Chlorine was discovered and first isolated by Carl Wilhelm Scheele in 1774. It was first recognized as an element by Humphry Davy in 1808.

Strontium

See more Strontium products. Strontium (atomic symbol: Sr, atomic number: 38) is a Block S, Group 2, Period 5 element with an atomic weight of 87.62 . Strontium Bohr ModelThe number of electrons in each of Strontium's shells is [2, 8, 18, 8, 2] and its electron configuration is [Kr] 5s2. The strontium atom has a radius of 215 pm and a Van der Waals radius of 249 pm. Strontium was discovered by William Cruickshank in 1787 and first isolated by Humphry Davy in 1808. In its elemental form, strontium is a soft, silvery white metallic solid that quickly turns yellow when exposed to air. Elemental StrontiumCathode ray tubes in televisions are made of strontium, which are becoming increasingly displaced by other display technologies pyrotechnics and fireworks employ strontium salts to achieve a bright red color. Radioactive isotopes of strontium have been used in radioisotope thermoelectric generators (RTGs) and for certain cancer treatments. In nature, most strontium is found in celestite (as strontium sulfate) and strontianite (as strontium carbonate). Strontium was named after the Scottish town where it was discovered.

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