Three-dimensional organometallic thallium(I) supramolecular polymer nanostructures synthesized with sonochemical process.

Title Three-dimensional organometallic thallium(I) supramolecular polymer nanostructures synthesized with sonochemical process.
Authors M. Moeinian; K. Akhbari; J. Boonmak; S. Youngme
Journal Ultrason Sonochem
DOI 10.1016/j.ultsonch.2017.09.008
Abstract

A new three-dimensional thallium(I) supramolecular polymer, [Tl2(?2-ATA)]n (1), [H2ATA=2-aminoterephthalic acid], has been synthesized and characterized. The single-crystal X-ray data of compound 1 shows one type of TlI ion with a low coordination number. Compound 1 was self-assembled from Tl?C, Tl?O and Tl?N secondary interactions in thallium(I) coordination and the active lone pair on TlI in this compound may be involved in donor bonding. Two sides of the aromatic ring of ATA2- anion have been involved in two types of secondary Tl?C approaches. Three samples of 1 were synthesized with three different concentrations of initial reagents under ultrasonic irradiation. The thermal stability of compound 1 samples were studied by thermo gravimetric (TG) and differential thermal analyses (DTA). These nano-structures were characterized by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM).

Citation M. Moeinian; K. Akhbari; J. Boonmak; S. Youngme.Three-dimensional organometallic thallium(I) supramolecular polymer nanostructures synthesized with sonochemical process.. Ultrason Sonochem. 2018;41:1116. doi:10.1016/j.ultsonch.2017.09.008

Related Elements

Thallium

See more Thallium products. Thallium (atomic symbol: Tl, atomic number: 81) is a Block P, Group 13, Period 6 element with an atomic weight of 204.38. Thallium Bohr ModelThe number of electrons in each of thallium's shells is 2, 8, 18, 32, 18, 3 and its electron configuration is [Xe] 4f14 5d10 6s2 6p1. The thallium atom has a radius of 170 pm and a Van der Waals radius of 196 pm. Thallium was discovered by Sir William Crookes in 1861 and first isolated by Claude-Auguste Lamy in 1862. Thallium is a post-transition metal that is not found free in nature. Thallium is primarily used for its electrical conductivity as thallium sulfide, which changes with exposure to infrared light. This ability makes the compound useful in photocells. Elemental ThalliumThallium bromide-iodide crystals have been used as infrared optical materials. Thallium has also been used with sulfur, selenium or arsenic to produce low melting glasses which become fluid between 125 and 150 °C, while thallium oxide has been used to produce glasses with a high index of refraction, and is also used in the manufacture of photo cells. Its name is derived from the Greek word thallos, which means twig or green shoot.

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