SECTION 2. HAZARDS IDENTIFICATION
GHS-US classification
Skin corrosion/irritation Category 2 H315 Causes skin irritation
Serious eye damage/eye irritation Category 2A H319 Causes serious eye irritation
Full text of H statements : see section 16
Signal word (GHS US) : Warning
Hazard statements (GHS US) : H315 - Causes skin irritation
H319 - Causes serious eye irritation
Precautionary statements (GHS US) : P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P264 - Wash hands thoroughly after handling.
P302+P352 - If on skin: Wash with plenty of soap and water
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing
P337+P313 - If eye irritation persists: Get medical advice/attention.
P321 - Specific treatment (see first aid instructions on this label)
P362+P364 - Take off contaminated clothing and wash it before reuse
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance type : Multi-constituent
Name : BIS(NEODECANOATE)TIN, tech-90
CAS-No. : 49556-16-3
SECTION 4. FIRST AID MEASURES
Description of first aid measures:
First-aid measures general : Remove contaminated clothing and shoes. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). If possible show this sheet; if not available show packaging or label. IF exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If you feel unwell, seek medical advice.
First-aid measures after skin contact : Wash with plenty of soap and water. Get medical advice/attention.
First-aid measures after eye contact : Immediately flush eyes thoroughly with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion : Never give anything by mouth to an unconscious person. Get medical advice/attention.
Most important symptoms and effects (acute and delayed):
Symptoms/effects after inhalation : May cause irritation to the respiratory tract. Overexposure may cause: Coughing. Headache.
Nausea.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
Symptoms/effects after ingestion : May be harmful if swallowed.
Immediate medical attention and special treatment, if necessary:
Note to physician: Application of corticosteroid creams has been effective in treating severe skin irritation. If blisters develop, they may require
abrasion to promote healing.
SECTION 5. FIREFIGHTING MEASURES
Suitable (and unsuitable) extinguishing media:
Suitable extinguishing media : Water spray. Foam. Carbon dioxide. Dry chemical.
Unsuitable extinguishing media : Do not use straight streams.
Specific hazards arising from the chemical:
Fire hazard : Irritating fumes and organic acid vapors may develop when material is exposed to elevated temperatures or open flame.
Special protective equipment and precautions for fire-fighters:
Firefighting instructions : Use water spray to cool exposed surfaces. Exercise caution when fighting any chemical fire.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
Avoid all eye and skin contact and do not breathe vapor and mist.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Protective equipment : Wear protective equipment as described in Section 8.
Emergency procedures : Evacuate unnecessary personnel.
For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection".
Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Methods and material for containment and cleaning up
For containment : Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams.
Methods for cleaning up : Clean up any spills as soon as possible, using an absorbent material to collect it. Sweep or shovel spills into appropriate container for disposal.
SECTION 7. HANDLING AND STORAGE
Precautions for safe handling
Precautions for safe handling : Avoid all eye and skin contact and do not breathe vapor and mist. Provide good ventilation in process area to prevent accumulation of vapors.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash contaminated clothing before reuse.
Conditions for safe storage, including any incompatibilities
Storage conditions : Keep container tightly closed.
Incompatible materials : Oxidizing agent. Direct sunlight.
Storage area : Store in a well-ventilated place. Store away from heat.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Appropriate engineering controls
Appropriate engineering controls : Provide local exhaust or general room ventilation.
Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure.
Hand protection:
Neoprene or nitrile rubber gloves
Eye protection:
Chemical goggles. Contact lenses should not be worn
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. NIOSH-certified combination organic vapor/acid gas (yellow cartridge) respirator.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state : Liquid
Appearance : Liquid. Viscous.
Molecular mass : 461.23 g/mol
Color : Amber.
Odor : Mild.
Odor threshold : No data available
Refractive index : 1.487
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : No data available
Freezing point : < 0 °C
Boiling point : No data available
Flash point : > 110 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapor pressure : 14 mm Hg @ 140°C
Relative vapor density at 20 °C : No data available
Relative density : 1.16
% Volatiles : < 3 %
Solubility : Insoluble in water.
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Explosion limits : No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity
No additional information available
Chemical stability
Stable in sealed containers stored under a dry inert atmosphere. Oxidizes slowly in the presence of air.
Possibility of hazardous reactions
Direct sunlight causes slow degradation to an inorganic tin salt.
Conditions to avoid
Heat. Open flame. Sparks.
Incompatible materials
Oxidizing agent. Direct sunlight.
Hazardous decomposition products
Organic acid vapors. Tin oxides.
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity : Not classified
Neodecanoic acid (26896-20-8)
LD50 oral rat 2000 mg/kg
LD50 dermal rabbit > 3160 mg/kg
LC50 inhalation rat > 3000 mg/kg
ATE US (oral) 2000 mg/kg body weight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity – single exposure : Not classified
Specific target organ toxicity – repeated
exposure
: Not classified
Aspiration hazard : Not classified
Symptoms/effects after inhalation : May cause irritation to the respiratory tract. Overexposure may cause: Coughing. Headache.
Nausea.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
Symptoms/effects after ingestion : May be harmful if swallowed.
Reason for classification : Expert judgment
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Ecology - water : Toxic to aquatic life.
Persistence and degradability
No additional information available
1
Bioaccumulative potential
No additional information available
Mobility in soil
No additional information available
Other adverse effects
Other adverse effects : This substance may be hazardous to the environment.
Effect on the ozone layer : No additional information available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Sewage disposal recommendations : Do not dispose of waste into sewer.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.
Ecology - waste materials : Avoid release to the environment.
SECTION 14. TRANSPORT INFORMATION
UN number
Not regulated for transport.
UN proper shipping name
Not applicable
Additional information
Other information : No supplementary information available.
SECTION 15. REGULATORY INFORMATION
Tin(2+) neodecanoate (49556-16-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Neodecanoic acid (26896-20-8)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
International regulations
CANADA
Tin(2+) neodecanoate (49556-16-3)
Listed on the Canadian NDSL (Non-Domestic Substances List)
Neodecanoic acid (26896-20-8)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
Tin(2+) neodecanoate (49556-16-3)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Neodecanoic acid (26896-20-8)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
National regulations
Tin(2+) neodecanoate (49556-16-3)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Neodecanoic acid (26896-20-8)
Not listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
US State regulations
California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental
and/or reproductive harm
