SECTION 2. HAZARDS IDENTIFICATION

Signal Word: Warning

Hazard Statements: H228: Flammable solid
H302+H312+H332: Harmful if swallowed, in contact with skin or if inhaled
H315: Causes skin irritation
H319: Causes serious eye irritation
H335: May cause respiratory irritation
Precautionary Statements: P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking
P240: Ground/bond container and receiving equipment
P241: Use explosion-proof electrical/ventilating/lighting/equipment
P261: Avoid breathing dust/fume/gas/mist/vapors/spray
P280: Wear protective gloves/protective clothing/eye protection/face protection
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P302+P352: IF ON SKIN: Wash with soap and water
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing
P370+P378: In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction
HMIS Health Ratings (0-4):
Health: 1
Flammability: 2
Physical: 2

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Family: Inorganic Compound
Additional Names: None
Titanium Phosphide (TiP)
Percentage: 100 wt%
CAS #: 12037-65-9
EC #: 243-862-6

SECTION 4. FIRST AID MEASURES

General Treatment: Seek medical attention if symptoms persist.
Special Treatment: None
Important Symptoms: N/A
Inhalation: Remove victim to fresh air. Supply oxygen if breathing is difficult. Seek medical attention.
Ingestion: Rinse mouth with water. Do not induce vomiting. Seek medical attention.
Skin: Wash affected area with mild soap and water. Remove any contaminated clothing. Seek medical attention.
Eyes: Flush eyes with water, blinking often for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Seek medical attention.

SECTION 5. FIREFIGHTING MEASURES

Flammability: Flammable
Extinguishing Media: Do not use water for metal fires. Use class D or other metal extinguishing agent.
Spec. Fire Fighting Procedure: Use full-face, self-contained breathing apparatus with full protective clothing to prevent contact with skin and eyes. See section 10 for decomposition products.

SECTION 6. ACCIDENTAL RELEASE MEASURES

If Material Is Released/Spilled: Wear appropriate respiratory and protective equipment specified in special protection information. Isolate spill area and provide ventilation. Vacuum up spill using a high efficiency particulate absolute (HEPA) air filter and place in a closed container for disposal. Take care not to raise dust.
Environmental Precautions: Isolate runoff to prevent environmental pollution.

SECTION 7. HANDLING AND STORAGE

Handling Conditions: Wash thoroughly after handling.
Storage Conditions: Store in a cool dry place in a tightly sealed container. Store apart from materials and conditions listed in section 10.
Work/Hygienic Maintenance: Do not use tobacco or food in work area. Wash thoroughly before eating and smoking. Do not blow dust off clothing or skin with compressed air.
Ventilation: Provide sufficient ventilation to maintain concentration at or below threshold limit.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Permissible Exposure Limits: N/A
Threshold Limit Value: N/A
Special Equipment: None
Respiratory Protection: Use a recommended dust respirator or mask. Only use equipment tested and approved under appropriate government standards.
Protective Gloves: Nitrile or rubber gloves
Eye Protection: Safety glasses or goggles
Body Protection: Protective work clothing. Wear close-toed shoes and long sleeves/pants.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Color Metallic grey
Form: Powder, Granules, Pellets, Sputtering target, Custom parts
Odor: N/A
Water Solubility: Insoluble
Boiling Point: N/A
Melting Point: 1900 °C
Flash Point: N/A
Autoignition Temperature: N/A
Density: 3.95 gm/ml
Molecular weight: 78.84 g/mol

SECTION 10. STABILITY AND REACTIVITY

Stability: Stable under recommended storage conditions
Reacts With: Oxidizing agents, Water, Steam moisture, Acids and Acid fumes
Incompatible Conditions: Heat, Flames, Sparks and other Ignition sources
Hazardous Decomposition Products: Titanium oxides, Phosphorous oxides and Hydrogen Phosphide (Phosphine)

SECTION 11. TOXICOLOGICAL INFORMATION

Potential Health Effects:
Eyes: Causes serious irritation
Skin: Harmful in contact
Ingestion: Harmful if swallowed
Inhalation: Harmful if inhaled
Chronic: N/A
Signs & Symptoms: N/A
Aggravated Medical Conditions: N/A
Median Lethal Dose: N/A
Carcinogen: N/A

SECTION 12. ECOLOGICAL INFORMATION

Aquatic Toxicity: N/A
Persistent Bioaccumulation Toxicity: N/A
Very Persistent, Very Bioaccumulative: N/A
Notes: N/A

SECTION 13. DISPOSAL CONSIDERATIONS

Dispose of in accordance with local, state, national, and international regulations.

SECTION 14. TRANSPORT INFORMATION

Hazardous: Hazardous as powder only
Hazard Class: 4.1 Flammable Solids
Packing Group: III
UN Number: UN 3178
Proper Shipping Name: Flammable solid, inorganic, n.o.s. (Titanium Phosphide)

SECTION 15. REGULATORY INFORMATION

Sec 302 Extremely Hazardous: No
Sec 304 Reportable Quantities: N/A
Sec 313 Toxic Chemicals: N/A