SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS06 skull and crossbones
Acute Tox. 2 H300 Fatal if swallowed.
Acute Tox. 2 H310 Fatal in contact with skin.
Acute Tox. 2 H330 Fatal if inhaled.
GHS08 health hazard
Muta. 1A H340 May cause genetic defects.
Carc. 1A H350 May cause cancer.
GHS09 environment
Aquatic Acute 1 H400 Very toxic to aquatic life.
Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
N/A
Information concerning particular hazards for human and environment:
N/A
Label elements
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation.
Hazard pictograms

GHS06
GHS08
GHS09
Signal word
Danger
Hazard-determining components of labelling:
Tris(dimethylamino)arsine
Hazard statements
H300+H310+H330 Fatal if swallowed, in contact with skin or if inhaled.
H340 May cause genetic defects.
H350 May cause cancer.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P231 Handle under inert gas.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P422 Store contents under inert gas.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Other hazards
Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterisation: Substances
CAS # / Substance Name
6596-96-9 Tris(dimethylamino)arsine

SECTION 4. FIRST AID MEASURES

Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Remove breathing equipment only after contaminated clothing have been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
If inhaled:
Supply fresh air or oxygen; call for doctor.
In case of unconsciousness place patient stably in side position for transportation.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Do not induce vomiting; call for medical help immediately.
Most important symptoms and effects, both acute and delayed
No data available
Indication of any immediate medical attention and special treatment needed
No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture
No data available
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Not required.
Environmental precautions:
Inform respective authorities in case of seepage into water courses, or sewage systems.
Methods and materials for containment and cleanup:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Handling:
Handle under inert gas.
Information about fire - and explosion protection:
Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities:
Store contents under inert gas.
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Not required.
Further information about storage conditions:
Keep container tightly sealed.
Specific end use(s)
No data available

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical facilities:
No further data; see item 7.
Control parameters
Ingredients with limit values that require monitoring at the workplace:
Not required.
Additional information:
The lists valid during the making were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Eye protection:
Tightly sealed goggles

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

General Information
Appearance:
Form: Liquid
Colour: Colourless
Odor: Amine-like
Odor threshold: No data available.
pH: No data available.
Melting point/Melting range: No data available.
Boiling point/Boiling range: Undetermined.
Flash point: N/A
Flammability (solid, gas): N/A
Decomposition temperature: No data available.
Self-igniting: No data available.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: No data available.
Upper: No data available.
Vapor pressure: no data hPa
Density: No data available.
Relative density
No data available.
Vapor density
No data available.
Evaporation rate
No data available.
Solubility in / Miscibility with water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: No data available.
Kinematic: No data available.
Solvent content:
Organic solvents: 0.0 %
VOC (EC)
0.00 %
Other information
No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity
Chemical stability
Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No data available
Incompatible materials:
No data available
Hazardous decomposition products:
No dangerous decomposition products known.

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin:
No irritant effect.
on the eye:
No irritating effect.
Sensitisation:
No sensitising effects known.
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
Muta. 1A, Carc. 1A

SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Ecotoxical effects:
Remark:
Very toxic for fish
Additional ecological information:
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A
Other adverse effects
No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Must not be disposed together with household garbage. Do not allow product to enter drains, sewage systems, or other water courses system.
Uncleaned packaging:
Recommendation:
Disposal must be made according to official regulations.

SECTION 14. TRANSPORT INFORMATION

UN-Number
ADR, IMDG, IATA
UN1556
UN proper shipping name
ADR
1556 ARSENIC COMPOUND, LIQUID, N.O.S.
IMDG, IATA
ARSENIC COMPOUND, LIQUID, N.O.S.
14.3 Transport hazard class(es)
ADR, IMDG
Class
6
Label
6.1
IATA
Class
6.1 Toxic substances.
Label
6.1
Packing group
ADR, IMDG, IATA
II
Environmental hazards:
Marine pollutant:
No
Special precautions for user
N/A
EMS Number: F-A,S-A
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N/A
Transport/Additional information:
ADR
Limited quantities (LQ)
.1L
Excepted quantities (EQ)
Code: E4
Maximum net quantity per inner packaging: 1 ml
Maximum net quantity per outer packaging: 500 ml
IMDG
Limited quantities (LQ)
.1L
Excepted quantities (EQ)
Code: E4
Maximum net quantity per inner packaging: 1 ml
Maximum net quantity per outer packaging: 500 ml
UN "Model Regulation":
UN1556, ARSENIC COMPOUND, LIQUID, N.O.S., 6.1, II

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations:
Information about limitation of use:
Workers are not allowed to be exposed to this hazardous material. Exceptions can be made by the authorities in certain cases.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.