SECTION 2. HAZARDS IDENTIFICATION

Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Flammable solids: Category 2
Skin Corrosion/irritation: Category 2
Serious Eye Damage/Eye Irritation: Category 2
Specific target organ toxicity (single exposure): Category 3
Target Organs - Respiratory system.
Label Elements
Signal Word: Warning
Hazard Statements
Flammable solid
Causes skin irritation
Causes serious eye irritation
May cause respiratory irritation

Precautionary Statements
Prevention
Ground/bond container and receiving equipment
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Use explosion-proof electrical/ventilating/lighting/equipment
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician if you feel unwell
Skin
IF ON SKIN: Wash with plenty of soap and water
If skin irritation occurs: Get medical advice/attention
Take off contaminated clothing and wash before reuse
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
Fire
In case of fire: Use CO2, dry chemical, or foam for extinction
Storage
Store in a well-ventilated place. Keep container tightly closed
Store locked up
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
None identified

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component: Tungsten(VI) ethoxide
CAS-No: 62571-53-3
Weight %: <=100

SECTION 4. FIRST AID MEASURES

General Advice If symptoms persist, call a physician.
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.
Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.
Inhalation Move to fresh air. If not breathing, give artificial respiration. Get medical attention if
symptoms occur.
Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attention if
symptoms occur.
Most important symptoms and effects
None reasonably foreseeable.
Notes to Physician Treat symptomatically

SECTION 5. FIREFIGHTING MEASURES

Suitable Extinguishing Media Carbon dioxide (CO 2). Dry powder. Foam. Water may be ineffective.
Unsuitable Extinguishing Media No information available
Flash Point No information available
Method - No information available
Autoignition Temperature No information available
Explosion Limits
Upper No data available
Lower No data available
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the Chemical
Keep product and empty container away from heat and sources of ignition.
Hazardous Combustion Products
Tungsten oxides
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
NFPA
Health: 2
Flammability: 2
Instability: 0
Physical hazards: -

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Ensure adequate ventilation. Use personal protective equipment. Avoid dust formation.
Environmental Precautions Should not be released into the environment. See Section 12 for additional ecological information. Do not allow material to contaminate ground water system. Do not flush into surface water or sanitary sewer system.
Methods for Containment and Clean Up
Sweep up or vacuum up spillage and collect in suitable container for disposal. Keep in
suitable, closed containers for disposal.

SECTION 7. HANDLING AND STORAGE

Handling
Wear personal protective equipment. Ensure adequate ventilation. Do not get in eyes, on
skin, or on clothing. Avoid ingestion and inhalation. Avoid dust formation.
Storage
Keep containers tightly closed in a dry, cool and well-ventilated place.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.
Engineering Measures Ensure that eyewash stations and safety showers are close to the workstation location.
Personal Protective Equipment
Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin and body protection: Long sleeved clothing.
Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Solid
Appearance Off-white - Brown
Odor No information available
Odor Threshold No information available
pH No information available
Melting Point/Range 150 °C / 302 °F
Boiling Point/Range No information available
Flash Point No information available
Evaporation Rate Not applicable
Flammability (solid,gas) No information available
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure No information available
Vapor Density Not applicable
Specific Gravity No information available
Solubility No information available
Partition coefficient; n-octanol/water No data available
Autoignition Temperature No information available
Decomposition Temperature No information available
Viscosity Not applicable
Molecular Formula C12 H30 O6 W
Molecular Weight 454.21

SECTION 10. STABILITY AND REACTIVITY

Reactive Hazard None known, based on information available
Stability Moisture sensitive.
Conditions to Avoid Incompatible products.
Incompatible Materials Oxidizing agents
Hazardous Decomposition Products Tungsten oxides
Hazardous Polymerization Hazardous polymerization does not occur.
Hazardous Reactions None under normal processing.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute Toxicity
Product Information
Component Information
Toxicologically Synergistic
Products
No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation No information available
Sensitization No information available
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Mutagenic Effects No information available
Reproductive Effects No information available.
Developmental Effects No information available.
Teratogenicity No information available.
STOT - single exposure Respiratory system
STOT - repeated exposure None known
Aspiration hazard No information available
Symptoms / effects,both acute and delayed
No information available
Endocrine Disruptor Information No information available
Other Adverse Effects The toxicological properties have not been fully investigated.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
May cause long-term adverse effects in the environment. Do not allow material to contaminate ground water system.
Persistence and Degradability May persist
Bioaccumulation/ Accumulation No information available.
Mobility No information available.

SECTION 13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.

SECTION 14. TRANSPORT INFORMATION

DOT
UN-No UN3181
Proper Shipping Name METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S.
Proper technical name (Tungsten(VI) ethoxide)
Hazard Class 4.1
Packing Group III
TDG
UN-No UN3181
Proper Shipping Name METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S.
Hazard Class 4.1
Packing Group III
IATA
UN-No UN3181
Proper Shipping Name METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S.*
Hazard Class 4.1
Packing Group III
IMDG/IMO
UN-No UN3181
Proper Shipping Name METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S.
Hazard Class 4.1
Packing Group III

SECTION 15. REGULATORY INFORMATION

U.S. Federal Regulations
TSCA 12(b) Not applicable
SARA 313 Not applicable
SARA 311/312 Hazard Categories See section 2 for more information
CWA (Clean Water Act) Not applicable
Clean Air Act Not applicable
OSHA Occupational Safety and Health Administration
Not applicable
CERCLA Not applicable
California Proposition 65 This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know
Regulations
Not applicable
U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant N
DOT Severe Marine Pollutant N
U.S. Department of Homeland Security
This product does not contain any DHS chemicals.
Other International Regulations
Mexico - Grade No information available