Two-dimensional coordination polymeric structures in the sodium, potassium and rubidium complex salts with (4-fluorophenoxy)acetic acid.

Title Two-dimensional coordination polymeric structures in the sodium, potassium and rubidium complex salts with (4-fluorophenoxy)acetic acid.
Authors G. Smith
Journal Acta Crystallogr C Struct Chem
DOI 10.1107/S2053229617014103
Abstract

The structures of the sodium, potassium and rubidium complex salts of (4-fluorophenoxy)acetic acid (PFPA), namely poly[?-aqua-aqua-?-[2-(4-fluorophenoxy)acetato]-?3O1,O2:O1'-sodium], [Na(C8H6FO3)(H2O)2]n, (I), and isotypic poly[?5-[2-(4-fluorophenoxy)acetato]-?5O1,O2:O1,O1':O1':O1':O1'-potassium], [K(C8H6FO3)]n, (II), and poly[?5-[2-(4-fluorophenoxy)acetato]-?5O1,O2:O1,O1':O1':O1':O1'-rubidium], [Rb(C8H6FO3)]n, (III), have been determined and their coordination polymeric structures described. In the structure of (I), the very distorted octahedral NaO6 coordination polyhedron comprises two bidentate chelating O-atom donors (carboxylate and phenoxy) of the PFPA ligand and three O-atom donors from water molecules, one monodentate and the other ?2-bridging between inversion-related Na centres in a cyclic manner. A bridging carboxylate donor generates two-dimensional polymer layers lying parallel to (001), in which intralayer water O-H...O hydrogen-bonding associations are also present. Structures (II) and (III) are isotypic, each having an irregular MO7 stereochemistry, with the primary metal-ligand bidentate chelate similar to that in (I) and extended into a two-dimensional polymeric layered structure, lying parallel to (100), through five additional bridging carboxylate O atoms. Two of these bonds are from an O,O'-bidentate chelate interaction and the other three are from ?3-O-atom bridges, generating cyclic links with short M...M separations [3.9064?(17)?Å for (II) and 4.1001?(8) for (III)], the shortest being a centrosymmetric four-membered cyclic link. In the crystals of (I)-(III), intralayer C-H...F interactions are present, but no ?-? ring interactions are found.

Citation G. Smith.Two-dimensional coordination polymeric structures in the sodium, potassium and rubidium complex salts with (4-fluorophenoxy)acetic acid.. Acta Crystallogr C Struct Chem. 2017;73(Pt 11):979983. doi:10.1107/S2053229617014103

Related Elements

Potassium

Elemental PotassiumSee more Potassium products. Potassium (atomic symbol: K, atomic number: 19) is a Block S, Group 1, Period 4 element with an atomic weight of 39.0983. The number of electrons in each of Potassium's shells is [2, 8, 8, 1] and its electron configuration is [Ar] 4s1. The potassium atom has a radius of 227.2 pm and a Van der Waals radius of 275 pm. Potassium was discovered and first isolated by Sir Humphrey Davy in 1807. Potassium is the seventh most abundant element on earth. It is one of the most reactive and electropositive of all metals and rapidly oxidizes. As with other alkali metals, potassium decomposes in water with the evolution of hydrogen because of its reacts violently with water, it only occurs in nature in ionic salts.Potassium Bohr Model In its elemental form, potassium has a silvery gray metallic appearance, but its compounds (such as potassium hydroxide) are more frequently used in industrial and chemical applications. The origin of the element's name comes from the English word 'potash,' meaning pot ashes, and the Arabic word qali, which means alkali. The symbol K originates from the Latin word kalium.

Rubidium

See more Rubidium products. Rubidium (atomic symbol: Rb, atomic number: 37) is a Block S, Group 1, Period 5 element with an atomic weight of 5.4678. The number of electrons in each of Rubidium's shells is [2, 8, 18, 8, 1] and its electron configuration is [Kr] 5s1. The rubidium atom has a radius of 248 pm and a Van der Waals radius of 303 pm. Rubidium Bohr ModelRubidium is highly reactive, with properties similar to other Group 1 alkali metals, e.g., rapid oxidation in air. In its elemental form, rubidium has a gray white appearance. Rubidium is found in the minerals lepidolite, leucite, pollucite, carnallite, and zinnwaldite as well as some potassium minerals. Rubidium was discovered by Robert Bunsen and Gustav Kirchhoff in 1861 and was first isolated by George de Hevesy. The name Rubidium, originates from the Latin word rubidus, meaning "dark or deepest red."

Sodium

Sodium Bohr ModelSee more Sodium products. Sodium (atomic symbol: Na, atomic number: 11) is a Block D, Group 5, Period 4 element with an atomic weight of 22.989769. The number of electrons in each of Sodium's shells is [2, 8, 1] and its electron configuration is [Ne] 3s1. The sodium atom has a radius of 185.8 pm and a Van der Waals radius of 227 pm. Sodium was discovered and first isolated by Sir Humphrey Davy in 1807. In its elemental form, sodium has a silvery-white metallic appearance. It is the sixth most abundant element, making up 2.6 % of the earth's crust. Sodium does not occur in nature as a free element and must be extracted from its compounds (e.g., feldspars, sodalite, and rock salt). The name Sodium is thought to come from the Arabic word suda, meaning "headache" (due to sodium carbonate's headache-alleviating properties), and its elemental symbol Na comes from natrium, its Latin name.

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