Two Unique Crystalline Semiconductor Zeolite Analogues Based on Indium Selenide Clusters.

Title Two Unique Crystalline Semiconductor Zeolite Analogues Based on Indium Selenide Clusters.
Authors C. Xue; D. Hu; Y. Zhang; H. Yang; X. Wang; W. Wang; T. Wu
Journal Inorg Chem
DOI 10.1021/acs.inorgchem.7b02718
Abstract

Developing the structural diversity of microporous zeolitic frameworks with integrated semiconducting properties is promising but remains a challenge. Reported here are two unique crystalline semiconductor zeolite analogues constructed from two kinds of indium selenide clusters with augmented ctn and zeolite-type sod networks. The intrinsic semiconducting nature in these In-Se domains gives rise to pore-size-dependent and visible-light-driven photocatalytic activity for organic dye degradation.

Citation C. Xue; D. Hu; Y. Zhang; H. Yang; X. Wang; W. Wang; T. Wu.Two Unique Crystalline Semiconductor Zeolite Analogues Based on Indium Selenide Clusters.. Inorg Chem. 2017;56(24):1476314766. doi:10.1021/acs.inorgchem.7b02718

Related Elements

Selenium

Selenium Bohr ModelSee more Selenium products. Selenium (atomic symbol: Se, atomic number: 34) is a Block P, Group 16, Period 4 element with an atomic radius of 78.96. The number of electrons in each of Selenium's shells is 2, 8, 18, 6 and its electron configuration is [Ar] 3d10 4s2 4p4. The selenium atom has a radius of 120 pm and a Van der Waals radius of 190 pm. Selenium is a non-metal with several allotropes: a black, vitreous form with an irregular crystal structure three red-colored forms with monoclinic crystal structures and a gray form with a hexagonal crystal structure, the most stable and dense form of the element. Elemental SeleniumOne of the most common uses for selenium is in glass production the red tint that it lends to glass neutralizes green or yellow tints from impurities in the glass materials. Selenium was discovered and first isolated by Jöns Jakob Berzelius and Johann Gottlieb Gahn in 1817. The origin of the name Selenium comes from the Greek word "Selênê," meaning moon.

Indium

See more Indium products. Indium (atomic symbol: In, atomic number: 49) is a Block P, Group 13, Period 5 element with an atomic weight of 114.818. The number of electrons in each of indium's shells is [2, 8, 18, 18, 3] and its electron configuration is [Kr] 4d10 5s2 5p1. The indium atom has a radius of 162.6 pm and a Van der Waals radius of 193 pm. Indium was discovered by Ferdinand Reich and Hieronymous Theodor Richter in 1863. Indium Bohr ModelIt is a relatively rare, extremely soft metal is a lustrous silvery gray and is both malleable and easily fusible. It has similar chemical properties to Elemental Indiumgallium such as a low melting point and the ability to wet glass. Fields such as optics and microelectronics that utilize semiconductor technology have wide uses for indium, especially in the form of Indiun Tin Oxide (ITO). Thin films of Copper Indium Gallium Selenide (CIGS) are used in high-performing solar cells. Indium's name is derived from the Latin word indicum, meaning violet.

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