Ultrasound augmented leaching of nickel sulfate in sulfuric acid and hydrogen peroxide media.

Title Ultrasound augmented leaching of nickel sulfate in sulfuric acid and hydrogen peroxide media.
Authors H. Li; S. Li; J. Peng; C. Srinivasakannan; L. Zhang; S. Yin
Journal Ultrason Sonochem
DOI 10.1016/j.ultsonch.2017.08.031
Abstract

A new method of preparation high purity nickel sulfate assisted by ultrasonic was studied. The process mechanism was analyzed by Inductively Coupled Plasma (ICP), X-ray diffraction (XRD), Scanning electron microscopy (SEM), and Energy dispersive X-ray spectrometry (EDS).The reaction mechanisms of oxidizing leaching and ultrasonic leaching were explored, respectively. Results showed that ultrasonic treatment peel off the oxide film on the surface of nickel. The leachate under strongly agitated, the yield rate of nickel sulfate was accelerate. And the reaction area was increased by the cavitation effect, the liquid-solid reaction was promoted, and the activation energy was reduced. The leaching rate of nickel reached 46.29% by conventional leaching, which takes about 5h. Under the same conditions, the ultrasonic leaching rate reached 40%, only half of the conventional leaching time. Concentration of leaching agent, reaction temperature, ultrasonic power, leaching time had significant effect on the enhancement of the leaching reaction with ultrasonic radiation. The leaching rate of 60.41% under the optimum experiment conditions as follows: sulfuric acid concentration 30%, hydrogen peroxide 10%, leaching temperature 333K, ultrasonic power 200W and leaching time 4h. The kinetic study of the system was investigated, and the reaction rates of conventional leaching and ultrasonic leaching were controlled by diffusion, and the apparent activation energies were 16.2kJ/mol and 11.83kJ/mol.

Citation H. Li; S. Li; J. Peng; C. Srinivasakannan; L. Zhang; S. Yin.Ultrasound augmented leaching of nickel sulfate in sulfuric acid and hydrogen peroxide media.. Ultrason Sonochem. 2018;40(Pt A):10211030. doi:10.1016/j.ultsonch.2017.08.031

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Nickel

See more Nickel products. Nickel (atomic symbol: Ni, atomic number: 28) is a Block D, Group 4, Period 4 element with an atomic weight of 58.6934. Nickel Bohr ModelThe number of electrons in each of nickel's shells is [2, 8, 16, 2] and its electron configuration is [Ar]3d8 4s2. Nickel was first discovered by Alex Constedt in 1751. The nickel atom has a radius of 124 pm and a Van der Waals radius of 184 pm. In its elemental form, nickel has a lustrous metallic silver appearance. Nickel is a hard and ductile transition metal that is considered corrosion-resistant because of its slow rate of oxidation. Elemental NickelIt is one of four elements that are ferromagnetic and is used in the production of various type of magnets for commercial use. Nickel is sometimes found free in nature but is more commonly found in ores. The bulk of mined nickel comes from laterite and magmatic sulfide ores. The name originates from the German word kupfernickel, which means "false copper" from the illusory copper color of the ore.

Sulfur

See more Sulfur products. Sulfur (or Sulphur) (atomic symbol: S, atomic number: 16) is a Block P, Group 16, Period 3 element with an atomic radius of 32.066. Sulfur Bohr ModelThe number of electrons in each of Sulfur's shells is 2, 8, 6 and its electron configuration is [Ne] 3s2 3p4. In its elemental form, sulfur has a light yellow appearance. The sulfur atom has a covalent radius of 105 pm and a Van der Waals radius of 180 pm. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, and epsom salts. Sulfur has been known since ancient times but was not accepted as an element until 1777, when Antoine Lavoisier helped to convince the scientific community that it was an element and not a compound.

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