SECTION 2. HAZARDS IDENTIFICATION
GHS classification
Classification of the substance or mixture
Acute toxicity - Oral Category 4
Serious eye damage/eye irritation Category 2A
Signal word: Warning
Hazard statements:
H302 - Harmful if swallowed
H319 - Causes serious eye irritation
Precautionary statements:
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Wear protective gloves, protective clothing, eye protection, face protection
IF IN EYES:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF SWALLOWED:
Call a POISON CENTER or doctor/physician if you feel unwell
Rinse mouth.
Dispose of contents/container to an approved waste disposal plant.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name: Vanadyl Oxalate
Weight- 20.0-25.0 (vanadium), 35.0-45.0 (C2O4)%
CAS No. 15500-04-6
SECTION 4. FIRST AID MEASURES
Inhalation:
Remove to fresh air. If symptoms persist, call a physician.
Skin contact:
Wash off immediately with soap and plenty of water. If symptoms persist, call a physician.
Eye contact:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediate medical attention is required.
Ingestion:
Rinse mouth. Never give anything by mouth to an unconscious person. Call a physician or poison control center immediately. Do not induce vomiting without medical advice.
Protection of first-aiders:
Use personal protective equipment as required.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media:
Water spray (fog), Carbon dioxide (CO2), Foam, Extinguishing powder, Sand
Unsuitable extinguishing media:
No information available
Special extinguishing method:
No information available
Specific hazards arising from the chemical product:
Thermal decomposition can lead to release of irritating and toxic gases and vapors.
Protection of fire-fighters:
Use personal protective equipment as required. Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures:
For indoor, provide adequate ventilation process until the end of working. Deny unnecessary entry other than the people involved by, for example, using a rope. While working, wear appropriate protective equipments to avoid adhering it on skin, or inhaling the gas. Work from windward, and retract the people downwind.
Environmental precautions:
To be careful not discharged to the environment without being properly handled waste water contaminated.
Methods and materials for contaminent and methods and materials for cleaning up:
Sweep up and gather scattered particles, and collect it in an empty airtight container.
Recoverly, neutralization:
No information available
Secondary disaster prevention measures:
Clean contaminated objects and areas thoroughly observing environmental regulations.
SECTION 7. HANDLING AND STORAGE
Handling
Technical measures:
Avoid contact with strong oxidizing agents. Use with local exhaust ventilation.
Precautions:
Do not rough handling containers, such as upsetting, falling, giving a shock, and dragging. Prevent leakage, overflow, and scattering. Not to generate steam and dust in vain. Seal the container after use. After handling, wash hands and face, and then gargle. In places other than those specified, should not be smoking or eating and drinking. Should not be brought contaminated protective equipment and gloves to rest stops. Deny unnecessary entry of non-emergency personnel to the handling area.
Safety handling precautions:
Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Storage
Storage conditions:
Store away from sunlight in well-ventilated place at room temperature (preferably cool). Keep container tightly closed. Store locked up.
Safe packaging material:
Glass
Incompatible substances:
Strong oxidizing agents
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering controls:
In case of indoor workplace, seal the source or use a local exhaust system. Provide the safety shower facility, and hand- and eye-wash facility. And display their position clearly.
Exposure limits:
This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.
Chemical Name: Vanadyl Oxalate
CAS No. 15500-04-6
ISHL (Japan): N/A
ACGIH: N/A
Personal protective equipment:
Respiratory protection: Dust mask
Hand protection: Protection gloves
Eye protection: Protective eyeglasses or chemical safety goggles
Skin and body protection: Long-sleeved work clothes
General hygiene considerations:
Handle in accordance with good industrial hygiene and safety practice.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Color: blue
Appearance: powder or mass
Odor: No data available
pH: No data available
Melting point/freezing point: No data available
Boiling point, initial boiling point and boiling range: No data available
Flash point: No data available
Evaporation rate: No data available
Flammability (solid, gas): No data available
Upper/lower flammability or explosive limits
Upper： No data available
Lower： No data available
Vapour pressure: No data available
Vapour density: No data available
Specific Gravity Relative density: No data available
Solubilities water : sparingly soluble
n-Octanol/water partition coefficient:(log Pow): No data available
Auto-ignition temperature: No data available
Decomposition temperature: No data available
Viscosity (coefficient of viscosity): No data available
Dynamic viscosity: No data available
SECTION 10. STABILITY AND REACTIVITY
Stability: Stable under recommended storage conditions.
Reactivity: No data available
Hazardous reactions:
None under normal processing
Conditions to avoid:
Extremes of temperature and direct sunlight
Incompatible materials:
Strong oxidizing agents
Hazardous decomposition products:
Carbon monooxide (CO), Carbon dioxide (CO2), Vanadium oxide
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity: No data available
Skin irritation/corrosion: No data available
Serious eye damage/ irritation: No data available
Respiratory or skin sensitization: No data available
Reproductive cell mutagenicity: No data available
Carcinogenicity: No data available
Reproductive toxicity: No data available
STOT-single exposure: No data available
STOT-repeated exposure: No data available
Aspiration hazard: No data available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity: No information available
Other data: No data available
Persistence and degradability: Degree of decomposition：37 % by BOD (METI Existing chemical safety inspections)
Bioaccumulative potential: No information available
Mobility in soil: No information available
Hazard to the ozone layer: No information available
SECTION 13. DISPOSAL CONSIDERATIONS
Waste from residues:
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated container and contaminated packaging:
Disposal should be in accordance with applicable regional, national and local laws and regulations.
SECTION 14. TRANSPORT INFORMATION
ADR/RID Not regulated
UN number - Proper shipping name:
UN classfication
Subsidiary hazard class
Packing group
Marine pollutant Not applicable
IMDG Not regulated
UN number - Proper shipping name:
UN classfication
Subsidiary hazard class
Packing group
Marine pollutant (Sea) Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: No information available
IATA Not regulated
UN number - Proper shipping name:
UN classfication
Subsidiary hazard class
Packing group
Environmentally Hazardous Substance Not applicable
SECTION 15. REGULATORY INFORMATION
International Inventories
EINECS/ELINCS -
TSCA -
Japanese regulations
Fire Service Act Not applicable
Poisonous and Deleterious
Substances Control Law
Deleterious Substances 3rd. Grade
Industrial Safety and Health Act Not applicable
Regulations for the carriage and storage of dangerous goods in ship
Not applicable
Civil Aeronautics Law Not applicable
Pollutant Release and Transfer
Register Law
Class 1
Class 1 - No. 321
Export Trade Control Order Not applicable
