Versatility of chlorination-promoted skeletal transformation pathways in C-fullerene.

Title Versatility of chlorination-promoted skeletal transformation pathways in C-fullerene.
Authors S.M. Sudarkova; O.N. Mazaleva; R.A. Konoplev-Esgenburg; S.I. Troyanov; I.N. Ioffe
Journal Dalton Trans
DOI 10.1039/c8dt00245b
Abstract

We present the synthesis and crystal structure of a new chlorinated non-IPR isomer of Cfullerene,CCl. The new chloride is formed from IPR-D-Cvia a sequence of chlorination-promoted Stone-Wales rearrangements concurrently with the previously known non-IPR compoundCCl. A considerable difference between the two simultaneously forming non-IPR compounds suggests that higher fullerenes can exhibit a much higher versatility of skeletal transformations than the presently known compounds. Our theoretical analysis identifies yet further favorable Stone-Wales pathways in Cand predicts several stable non-IPR and non-classical (i.e. heptagon-containing) Cchlorides that may await experimental isolation.

Citation S.M. Sudarkova; O.N. Mazaleva; R.A. Konoplev-Esgenburg; S.I. Troyanov; I.N. Ioffe.Versatility of chlorination-promoted skeletal transformation pathways in C-fullerene.. Dalton Trans. 2018. doi:10.1039/c8dt00245b

Related Elements

Carbon

See more Carbon products. Carbon (atomic symbol: C, atomic number: 6) is a Block P, Group 14, Period 2 element. Carbon Bohr ModelThe number of electrons in each of Carbon's shells is 2, 4 and its electron configuration is [He]2s2 2p2. In its elemental form, carbon can take various physical forms (known as allotropes) based on the type of bonds between carbon atoms; the most well known allotropes are diamond, graphite, amorphous carbon, glassy carbon, and nanostructured forms such as carbon nanotubes, fullerenes, and nanofibers . Carbon is at the same time one of the softest (as graphite) and hardest (as diamond) materials found in nature. It is the 15th most abundant element in the Earth's crust, and the fourth most abundant element (by mass) in the universe after hydrogen, helium, and oxygen. Carbon was discovered by the Egyptians and Sumerians circa 3750 BC. It was first recognized as an element by Antoine Lavoisier in 1789.

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