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SECTION 2. HAZARDS IDENTIFICATION

CLP Classification - Regulation (EC) No 1272/2008
Health hazards
Based on available data, the classification criteria are not met
Physical hazards
Based on available data, the classification criteria are not met
Environmental hazards
Based on available data, the classification criteria are not met

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component / CAS-No / Weight %
Zinc citrate / 5990-32-9 / <=100

SECTION 4. FIRST AID MEASURES

Description of first aid measures
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes. Get medical attention immediately if symptoms occur.
Ingestion
Clean mouth with water and drink afterwards plenty of water. Get medical attention if
symptoms occur.
Inhalation
Remove to fresh air. Get medical attention immediately if symptoms occur. Self-Protection of the First Aider No special precautions required.
Most important symptoms and effects, both acute and delayed
None reasonably foreseeable
Notes to Physician
Treat symptomatically.

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam.
Extinguishing media which must not be used for safety reasons
No information available.
Special hazards arising from the substance or mixture
Thermal decomposition can lead to release of irritating gases and vapors.
Hazardous Combustion Products
None under normal use conditions.
Advice for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation. Use personal protective equipment as required. Avoid dust formation.
Environmental precautions
Should not be released into the environment. See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up
Sweep up and shovel into suitable containers for disposal. Avoid dust formation.
Reference to other sections
Refer to protective measures listed in Sections 8 and 13

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Wear personal protective equipment/face protection. Ensure adequate ventilation. Avoid contact with skin, eyes or clothing. Avoid ingestion and inhalation. Avoid dust formation.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work.
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Specific end use(s)
Use in laboratories

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Exposure limits
This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies
Biological limit values
This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies
Monitoring methods
BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust
Derived No Effect Level (DNEL) No information available
Predicted No Effect Concentration (PNEC)
No information available.
Exposure controls
Engineering Measures
None under normal use conditions.
Personal protective equipment
Eye Protection Wear safety glasses with side shields (or goggles) (European standard - EN 166)
Hand Protection Protective gloves
Skin and body protection Long sleeved clothing
Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information)
Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger
of cuts, abrasion. Remove gloves with care avoiding skin contamination.
Respiratory Protection No protective equipment is needed under normal use conditions.
Large scale/emergency use Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits
are exceeded or if irritation or other symptoms are experienced
Recommended Filter type: Particle filter 2
Small scale/Laboratory use Maintain adequate ventilation
Environmental exposure controls No information available.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Solid
Appearance White
Odor Odorless
Odor Threshold No data available
Melting Point/Range No data available
Softening Point No data available
Boiling Point/Range No information available
Flammability (liquid) Not applicable Solid
Flammability (solid,gas) No information available
Explosion Limits No data available
Flash Point No information available Method - No information available
Autoignition Temperature No data available
Decomposition Temperature No data available
pH No information available
Viscosity Not applicable Solid
Water Solubility No information available
Solubility in other solvents No information available
Partition Coefficient (n-octanol/water)
Vapor Pressure No data available
Density / Specific Gravity No data available
Bulk Density No data available
Vapor Density Not applicable

SECTION 10. STABILITY AND REACTIVITY

Reactivity None known, based on information available
Chemical stability
Stable under normal conditions.
Possibility of hazardous reactions
Hazardous Polymerization No information available. Hazardous Reactions None under normal processing.
Conditions to avoid
Incompatible products. Excess heat.
Incompatible materials
None known.
Hazardous decomposition products
None under normal use conditions

SECTION 11. TOXICOLOGICAL INFORMATION

Product Information
(a) acute toxicity;
Oral No data available
Dermal No data available
Inhalation No data available
(b) skin corrosion/irritation; No data available
(c) serious eye damage/irritation; No data available
(d) respiratory or skin sensitization;
Respiratory No data available
Skin No data available
(e) germ cell mutagenicity; No data available
(f) carcinogenicity; No data available
There are no known carcinogenic chemicals in this product
(g) reproductive toxicity; No data available
(h) STOT-single exposure; No data available
(i) STOT-repeated exposure; No data available
Target Organs No information available. (j) aspiration hazard; Not applicable
Solid
Symptoms / effects,both acute and delayed
No information available.
Information on other hazards
Endocrine Disrupting Properties
Assess endocrine disrupting properties for human health. This product does not contain any
known or suspected endocrine disruptors.

SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Ecotoxicity effects Contains no substances known to be hazardous to the environment or that are not degradable in waste water treatment plants.
Persistence and degradability No information available
Bioaccumulative potential No information available
Mobility in soil No information available
Results of PBT and vPvB assessment
No data available for assessment.
Endocrine disrupting properties
Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors
Other adverse effects
Persistent Organic Pollutant This product does not contain any known or suspected substance
Ozone Depletion Potential This product does not contain any known or suspected substance

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Waste from Residues/Unused Products
Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Consult local, regional, and national hazardous waste regulations to
ensure complete and accurate classification.
Contaminated Packaging
Empty remaining contents. Dispose of in accordance with local regulations. Do not re-use
empty containers.
European Waste Catalogue (EWC) According to the European Waste Catalog, Waste Codes are not product specific, but application specific.
Other Information Waste codes should be assigned by the user based on the application for which the product was used.

SECTION 14. TRANSPORT INFORMATION

MDG/IMO Not regulated
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
ADR Not regulated
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
IATA Not regulated
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Environmental hazards No hazards identified
Special precautions for user No special precautions required
Maritime transport in bulk according to IMO instruments
Not applicable, packaged goods

SECTION 15. REGULATORY INFORMATION

Regulation (EC) No 649/2012 of the European Parliament and of the Council of 4 July 2012 concerning the export and
import of dangerous chemicals
Not applicable
National Regulations
WGK Classification Water endangering class = 3 (self classification)
UK - Take note of Control of Substances Hazardous to Health Regulations (COSHH) 2002