Compound Formula	O₄SiZn₂
Molecular Weight	222.84 (undoped)
Appearance	White solid
Melting Point	1500 °C
Boiling Point	N/A
Density	4.0 g/cm³
Bulk Density	1450 kg/m³
Solubility in H2O	< 0.1 g/l (20 °C)
pH	7.0 (suspension in H₂O)
Exact Mass	221.812 g/mol
Monoisotopic Mass	219.815 g/mol

Zinc Silicate, Manganese-doped Health & Safety Information

Signal Word	Warning
Hazard Statements	H315-H319-H332-H335
Hazard Codes	Xi
Precautionary Statements	P261-P305+P351+P338
Risk Codes	N/A
Safety Statements	S22
Transport Information	NONH for all modes of transport
WGK Germany	1
GHS Pictograms	GHS07 Exclamation Point

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SAFETY DATA SHEET

Date Accessed: 11/22/2024

Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Zinc Silicate, Manganese-doped

Product Number: All applicable American Elements product codes, e.g. ZN-SIAT-018-C.MND

CAS #: 68611-47-2

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview
OSHA Hazards
Irritant
GHS Label elements, including precautionary statements

Signal word Warning
Hazard statement(s)
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
Precautionary statement(s)
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
HMIS Classification
Health hazard: 2
Flammability: 0
Physical hazards: 0
NFPA Rating
Health hazard: 2
Fire: 0
Reactivity Hazard: 0
Potential Health Effects
Inhalation May be harmful if inhaled. Causes respiratory tract irritation.
Skin May be harmful if absorbed through skin. Causes skin irritation.
Eyes Causes eye irritation.
Ingestion May be harmful if swallowed.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Synonyms : Zinc silicate, manganese-doped
Formula : Zn2SiO4:Mn
CAS: 68611-47-2

SECTION 4. FIRST AID MEASURES

General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special protective equipment for fire-fighters
Wear self contained breathing apparatus for fire fighting if necessary.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions
Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate
ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for
disposal.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire protection.
Conditions for safe storage
Keep container tightly closed in a dry and well-ventilated place.
Keep in a dry place.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Personal protective equipment
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection
use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components
tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Hand protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching
glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in
accordance with applicable laws and good laboratory practices. Wash and dry hands.
Eye protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin and body protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
Form powder
pH no data available
Melting point no data available
Boiling point no data available
Flash point not applicable
Ignition temperature no data available
Lower explosion limit no data available
Upper explosion limit no data available
Water solubility no data available

SECTION 10. STABILITY AND REACTIVITY

Chemical stability
Stable under recommended storage conditions.
Conditions to avoid
no data available
Materials to avoid
Strong oxidizing agents
Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Zinc oxides, silicon oxides

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure (Globally Harmonized System)
Inhalation - May cause respiratory irritation.
Specific target organ toxicity - repeated exposure (Globally Harmonized System)
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation May be harmful if inhaled. Causes respiratory tract irritation.
Ingestion May be harmful if swallowed.
Skin May be harmful if absorbed through skin. Causes skin irritation.
Eyes Causes eye irritation.
Signs and Symptoms of Exposure
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Additional Information

SECTION 12. ECOLOGICAL INFORMATION

Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
PBT and vPvB assessment
no data available
Other adverse effects
no data available

SECTION 13. DISPOSAL CONSIDERATIONS

Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.
Contaminated packaging
Dispose of as unused product.

SECTION 14. TRANSPORT INFORMATION

DOT (US)
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods

SECTION 15. REGULATORY INFORMATION

OSHA Hazards
Irritant
DSL Status
All components of this product are on the Canadian DSL list.
SARA 302 Components
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold
(De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards
Acute Health Hazard
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components
Zinc silicate
CAS-No.
68611-47-2
Revision Date
New Jersey Right To Know Components
Zinc silicate
CAS-No.
68611-47-2
Revision Date
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other
reproductive harm.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

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About Zinc Silicate, Manganese-doped

Manganese-doped (or manganese-activated) Zinc Silicate is a fluorescent phosphor material with green to yellow emission based on the feed solution pH. Please request a quote above to receive pricing information based on your specifications.

Zinc Silicate, Manganese-doped Synonyms

Zinc silicate manganese doped, dizinc orthosilicate, zinc orthosilicate manganese activated, Fluorescent indicator Green pH 7.0 (H₂O) suspension, willemite, Silicic acid (H4SiO4), zinc salt (1:2), manganese-doped, Zn₂SiO₄, Zn₂SiO₄:Mn, α-Zn2SiO4, β-Zn2SiO4, CAS 13597-65-4, EC 237-057-8

Chemical Identifiers

Linear Formula	Zn₂SiO₄:Mn²⁺
MDL Number	MFCD00049627
EC No.	271-896-0
Pubchem CID	15763952
IUPAC Name	dizinc; silicate
SMILES	[O-][Si]([O-])([O-])[O-].[Zn+2].[Zn+2]
InchI Identifier	InChI=1S/O4Si.2Zn/c1-5(2,3)4;;/q-4;2*+2
InchI Key	ZOIVSVWBENBHNT-UHFFFAOYSA-N

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Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Manganese

25 Mn 54.938045000 Manganese

See more Manganese products. Manganese (atomic symbol: Mn, atomic number: 25) is a Block D, Group 7, Period 4 element with an atomic weight of 54.938045. Manganese Bohr Model The number of electrons in each of Manganese's shells is [2, 8, 13, 2] and its electron configuration is [Ar] 3d⁵ 4s². The manganese atom has a radius of 127 pm and a Van der Waals radius of 197 pm. Manganese was first discovered by Torbern Olof Bergman in 1770 and first isolated by Johann Gottlieb Gahn in 1774. In its elemental form, manganese has a silvery metallic appearance. Elemental Manganese It is a paramagnetic metal that oxidizes easily in addition to being very hard and brittle. Manganese is found as a free element in nature and also in the minerals pyrolusite, braunite, psilomelane, and rhodochrosite. The name Manganese originates from the Latin word mangnes, meaning "magnet."

Silicon

14 Si 28.085500000 Silicon

See more Silicon products. Silicon (atomic symbol: Si, atomic number: 14) is a Block P, Group 14, Period 3 element with an atomic weight of 28.085. Silicon Bohr Molecule The number of electrons in each of Silicon's shells is 2, 8, 4 and its electron configuration is [Ne] 3s² 3p². The silicon atom has a radius of 111 pm and a Van der Waals radius of 210 pm. Silicon was discovered and first isolated by Jöns Jacob Berzelius in 1823. Silicon makes up 25.7% of the earth's crust, by weight, and is the second most abundant element, exceeded only by oxygen. The metalloid is rarely found in pure crystal form and is usually produced from the iron-silicon alloy ferrosilicon. Elemental Silicon Silica (or silicon dioxide), as sand, is a principal ingredient of glass, one of the most inexpensive of materials with excellent mechanical, optical, thermal, and electrical properties. Ultra high purity silicon can be doped with boron, gallium, phosphorus, or arsenic to produce silicon for use in transistors, solar cells, rectifiers, and other solid-state devices which are used extensively in the electronics industry.The name Silicon originates from the Latin word silex which means flint or hard stone.

Zinc

30 Zn 65.380000000 Zinc

See more Zinc products. Zinc (atomic symbol: Zn, atomic number: 30) is a Block D, Group 12, Period 4 element with an atomic weight of 65.38. The number of electrons in each of zinc's shells is 2, 8, 18, 2, and its electron configuration is [Ar] 3d¹⁰ 4s². Zinc Bohr Model The zinc atom has a radius of 134 pm and a Van der Waals radius of 210 pm. Zinc was discovered by Indian metallurgists prior to 1000 BC and first recognized as a unique element by Rasaratna Samuccaya in 800. Zinc was first isolated by Andreas Marggraf in 1746. In its elemental form, zinc has a silver-gray appearance. It is brittle at ordinary temperatures but malleable at 100 °C to 150 °C. Elemental Zinc It is a fair conductor of electricity, and burns in air at high red producing white clouds of the oxide. Zinc is mined from sulfidic ore deposits. It is the 24th most abundant element in the earth's crust and the fourth most common metal in use (after iron, aluminum, and copper). The name zinc originates from the German word "zin," meaning tin.