SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
STOT SE 3 H335 May cause respiratory irritation.
Label elements
GHS label elements
The substance is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS07
Signal word Warning
Hazard-determining components of labeling:
Zirconium 1,4-dicarboxybenzene MOF (UiO-66)
Hazard statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statements
P262 Do not get in eyes, on skin, or on clothing.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 - 4)
Health = 1
Fire = 0
Reactivity = 0
HMIS-ratings (scale 0 - 4)
Health = 1
Fire = 0
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
CAS # / Substance Name 1072413-80-9
Zirconium 1,4-dicarboxybenzene MOF (UiO-66)
SECTION 4. FIRST AID MEASURES
Description of first aid measures
If inhaled: In case of unconsciousness place patient stably in side position for transportation.
In case of skin contact: Immediately wash with soap and water; rinse thoroughly.
In case of eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
If swallowed: If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayed
No data available
Indication of any immediate medical attention and special treatment needed
No data available
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture
No data available
Advice for firefighters
Protective equipment: No special measures required
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures: Not Required
Enviornmental precautions: No Special measures required
Methods and materials for containment and cleanup: Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Refrence to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal prection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
Handling:
Precautions for safe handling: No special precautions are necessary if used correctly.
Information about protection against explosions and fires: No special measures required.
Conditions for safe storage, including any incimpatabilities
Storage:
Requirements to be met by storeooms and receptables: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Keep receptacle tightly sealed.
Specific end use(s): No data available
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems: No further data; see item 7
Control Parameters
Components with limit values that require monitoring at the workplace: Not required.
Additional information: The lists that were valid during the creation where used as basis.
Exposure controls
Personal protective equpment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intesive or longer exposure use respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be imperneable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
Material of Glove
The selection of the sutiable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
Penetration time of Glove Material
The exact break through time has to be found out by the manufacturer of the protective goves and has to be observed.
Eye Protection:
Tightly Sealed Goggles
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
General Information
Appearance:
Form: Powder
Color: White
Odor: Odorless
Odor threshold: No data available.
pH: N/A
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: Undetermined.
Flash point: N/A
Flammability (solid, gas): Product is not flammable.
Ignition temperature:
Decomposition temperature: No data available.
Autoignition: No data available.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: No data available.
Upper: No data available.
Vapor pressure: N/A
Density: No data available.
Relative density: No data available.
Vapor density: N/A
Evaporation rate: N/A
Solubility in Water (H2O): Insoluble.
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A
Kinematic: N/A
Solvent content:
Organic solvents: 0.0 %
VOC content: 0.0 g/l / 0.00 lb/gl
Solids content: 100.0 %
Other information: No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Possibility of hazardous reactions: No dangerous reactions known.
Conditions to avoid: No data available
Incompatible materials: No data available
Hazardous decomposition products: No dangerous decomposition products known.
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
Additional toxicological information:
Carcinogenic categories
IARC (International Agency for Research on Cancer)
Substance is not listed.
NTP (National Toxicology Program)
Substance is not listed.
OSHA-Ca (Occupational Safety & Health Administration)
Substance is not listed.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity: No data available
Persistence and degradability: No data available
Behavior in environmental systems:
Bioaccumulative potential: No data available
Mobility in soil: No data available
Additional ecological information:
General notes: Not known to be hazardous to water.
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A·
Other adverse effects: No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation: Must not be disposed of together with household garbage. Do not allow product to enter drains, sewage systems, or other water courses system.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
SECTION 14. TRANSPORT INFORMATION
UN-Number
DOT, ADN, IMDG, IATA
not regulated
UN proper shipping name
DOT, ADN, IMDG, IATA
not regulated
Transport hazard class(es)
DOT, ADN, IMDG, IATA
Class
not regulated
Packing group
DOT, IMDG, IATA
not regulated
Environmental hazards:
Marine pollutant: No
Special precautions for user
N/A
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
N/A
UN "Model Regulation":
not regulated
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
Substance is not listed.
Section 313 (Specific toxic chemical listings):
Substance is not listed.
TSCA (Toxic Substances Control Act):
Substance is not listed.
Proposition 65
Chemicals known to cause cancer:
Substance is not listed.
Chemicals known to cause reproductive toxicity for females:
Substance is not listed.·
Chemicals known to cause reproductive toxicity for males:
Substance is not listed.
Chemicals known to cause developmental toxicity:
Substance is not listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
Substance is not listed.
TLV (Threshold Limit Value established by ACGIH)
Substance is not listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
Substance is not listed.
GHS label elements
The substance is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS07
Signal word
Warning
Hazard-determining components of labeling:
Zirconium 1,4-dicarboxybenzene MOF (UiO-66)
Hazard statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statements
P262 Do not get in eyes, on skin, or on clothing.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if presentand easy to do. Continue rinsing.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.