SECTION 2. HAZARDS IDENTIFICATION

Classification (GHS-US)
Eye Irrit. 2A H319
Label elements
GHS-US labeling
Hazard pictograms (GHS-US)

Signal word: Warning
Hazard statements (GHS-US):
H319 -Causes serious eye irritation
Precautionary statements (GHS-US):
P280 -Wear protective gloves/protective clothing/eye protection/face protection
P264 -Wash hands thoroughly after handling
P305+P351+P338 -IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing
P337+P313 -If eye irritation persists: Get medical advice/attention
Other hazards
Other hazards not contributing to the classification:
Material may form zirconium oxides or zirconate polymers on the skin, eyes or in the lungs.
Prolonged exposure to zirconium compounds can induce formation of granulomatous lesions in
the lungs or on the skin.
Unknown acute toxicity (GHS US)
No data available

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance type: Mono-constituent
Name: ZIRCONIUM METHACRYLATE, 95%
CAS No: 67893-01-0
EC no: 267-604-6

SECTION 4. FIRST AID MEASURES

First-aid measures general: Remove contaminated clothing and shoes. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). If possible show this sheet; if not available show packaging or label.
First-aid measures If inhaled:
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If you feel
unwell, seek medical advice.
First-aid measures In case of skin contact:
Wash with plenty of soap and water.
First-aid measures In case of eye contact:
Immediately flush eyes thoroughly with water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion:
Never give anything by mouth to an unconscious person.
Get medical advice/attention.
Most important symptoms and effects, both acute and delayed
Symptoms/injuries If inhaled:
May cause irritation to the respiratory tract.
Symptoms/injuries In case of skin contact:
May cause skin irritation.
Symptoms/injuries In case of eye contact:
Causes serious eye irritation.
Symptoms/injuries after ingestion:
No data available.
Indication of any immediate medical attention and special treatment needed
No additional information available

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media:
Water spray. Foam. Carbon dioxide. Dry chemical.
Special hazards arising from the substance or mixture
Fire hazard:
Irritating fumes and organic acid vapors may develop when material is exposed to elevated
temperatures or open flame.
Advice for firefighters
Firefighting instructions:
Use water spray to cool exposed surfaces.
Exercise caution when fighting any chemical fire.
Protection during firefighting:
Do not enter fire area without proper protective equipment, including respiratory protection.
Avoid contact with skin and eyes. Do not breathe dust.

SECTION 6. ACCIDENTAL RELEASE MEASURES

For non-emergency personnel
Emergency procedures:
Evacuate unnecessary personnel.
For emergency responders
Protective equipment:
Equip cleanup crew with proper protection.
Environmental precautions
Prevent entry to sewers and public waters.
Methods and material for containment and cleaning up
Methods for cleaning up:
Sweep or shovel spills into appropriate container for disposal.
Reference to other sections
See Heading 8. Exposure controls and personal protection.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling:
Avoid contact with skin and eyes. Do not breathe dust. Provide local exhaust or general room
ventilation to minimize exposure to dust. Avoid dust formation.
Hygiene measures:
Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. W ash contaminated clothing before reuse.
Conditions for safe storage, including any incompatibilities conditions:
Keep container tightly closed.
Incompatible materials:
W ater

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
No additional information available
Exposure controls
Appropriate engineering controls:
Provide local exhaust or general room ventilation.
Personal protective equipment:
Avoid all unnecessary exposure. Emergency eye wash fountains and safety showers should be
available in the immediate vicinity of any potential exposure.
Hand protection:
Neoprene or nitrile rubber gloves.
Eye protection:
Chemical goggles. Contact lenses should not be worn.
Skin and body protection:
Wear suitable protective clothing.
Respiratory protection:
Where exposure through inhalation may occur from use, respiratory protection equipment is
recommended. NIOSH-certified dust and mist (orange cartridge) respirator.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Solid
Appearance: Solid.
Molecular mass: 431.55 g/mol
Color: Off-white.
Odor: No data available
Odor threshold: No data available
Refractive index : No data available
pH: No data available
Relative evaporation rate (butyl acetate=1): No data available
Melting point: 225 -230 °C decomposes
Freezing point: No data available
Boiling point: No data available
Flash point: > 110 °C
Auto-ignition temperature: No data available
Decomposition temperature: No data available
Flammability (solid, gas): No data available
Vapor pressure: No data available
Relative vapor density at 20 °C: No data available
Relative density: No data available
VOC content: < 5 %
Solubility: Insoluble in water. Reacts with water.
Organic solvent: isopropanol, THF
Log Pow: No data available
Log Kow: No data available
Viscosity, Kinematic: No data available
Viscosity, Dynamic: No data available
Explosive properties: No data available
Oxidizing properties: No data available
Explosion limits: No data available
Other information
No additional information available

SECTION 10. STABILITY AND REACTIVITY

Reactivity
No additional information available
Chemical stability
Stable.
Possibility of hazardous reactions
Material decomposes slowly in contact with water.
Conditions to avoid
Heat. Open flame. Sparks.
Incompatible materials
Water.
Hazardous decomposition products
Organic acid vapors. Zirconium oxide fumes.

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity: Not classified
Skin corrosion/irritation: Not classified
Serious eye damage/irritation: Causes serious eye irritation.
Respiratory or skin sensitization: Not classified
Germ cell mutagenicity: Not classified
Carcinogenicity: Not classified
Reproductive toxicity: Not classified
Specific target organ toxicity (single exposure): Not classified
Specific target organ toxicity (repeated exposure): Not classified
Aspiration hazard: Not classified
Symptoms/injuries If inhaled: May cause irritation to the respiratory tract.
Symptoms/injuries In case of skin contact: May cause skin irritation.
Symptoms/injuries In case of eye contact: Causes serious eye irritation.
Symptoms/injuries after ingestion: No data available.
Reason for classification: Expert judgment

SECTION 12. ECOLOGICAL INFORMATION

Toxicity
No additional information available
Persistence and degradability
No additional information available
Bioaccumulative potential
No additional information available
Mobility in soil
No additional information available
Other adverse effects
Effect on ozone layer: No additional information available
Effect on the global warming: No known ecological damage caused by this product.

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Waste disposal recommendations: Dispose of solid materials or residues at a licensed site. Dispose in a safe manner in accordance with local/national regulations.
Ecology -waste materials:
Avoid release to the environment.

SECTION 14. TRANSPORT INFORMATION

UN number
Not regulated for transport.
UN proper shipping name
N/A
Additional information
Other information:
No supplementary information available.
Transport by sea
No additional information available
Air transport
No additional information available

SECTION 15. REGULATORY INFORMATION

US Federal regulations
Zirconium methacrylate (67893-01-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
International regulations
Zirconium methacrylate (67893-01-0)
Listed on the Canadian NDSL (Non-Domestic Substances List)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
US State regulations
ZIRCONIUM METHACRYLATE, 95%(67893-01-0)
U.S. -California -Proposition 65-Carcinogens List
No
U.S. -California -Proposition 65-Developmental Toxicity
No
U.S. -California -Proposition 65-Reproductive Toxicity -Female
No
U.S. -California -Proposition 65 -Reproductive Toxicity -Male
No
Zirconium methacrylate (67893-01-0)
U.S. -California -Proposition 65-Carcinogens List
No
U.S. -California -Proposition 65-Developmental Toxicity
No
U.S. -California -Proposition 65 -Reproductive Toxicity -Female
No
U.S. -California -Proposition 65 -Reproductive Toxicity -Male
No
No significance risk level (NSRL)