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Copper Gallium Selenide

CAS #:

12018-83-6

Linear Formula:

CuGaSe₂

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ORDER

PRODUCT	Product Code	ORDER	SAFETY DATA	TECHNICAL DATA
(4N) 99.99% Copper Gallium Selenide Granules	CU-GASE-04-GR	Pricing >	SDS >	Data Sheet >
(4N) 99.99% Copper Gallium Selenide Powder	CU-GASE-04-P	Pricing >	SDS >	Data Sheet >
(5N) 99.999% Copper Gallium Selenide Granules	CU-GASE-05-GR	Pricing >	SDS >	Data Sheet >
(5N) 99.999% Copper Gallium Selenide Powder	CU-GASE-05-P	Pricing >	SDS >	Data Sheet >

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Copper Gallium Selenide Properties (Theoretical)

Compound Formula	CuGaSe₂
Molecular Weight	291.19
Appearance	Gray powder, granules, or sputtering target
Melting Point	1697 °C
Boiling Point	N/A
Density	5.56 g/cm³
Solubility in H2O	N/A
Crystal Phase / Structure	Tetragonal
Thermal Conductivity	4.20 W/m-K
Thermal Expansion	5.40 µm/m-°C
Exact Mass	291.688214 g/mol
Monoisotopic Mass	291.688214 g/mol

Copper Gallium Selenide Health & Safety Information

Signal Word	Danger
Hazard Statements	H300+H330-H373
Hazard Codes	T+
Precautionary Statements	P260-P284-P301+P310-P304+P340-P320-P405-P501
Risk Codes	N/A
Safety Statements	N/A
Transport Information	UN3077 9/PG III
GHS Pictograms	GHS06 Skull and Crossbones GHS08 Health Hazard

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SAFETY DATA SHEET

Date Accessed: 11/21/2024

Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Copper Gallium Selenide

Product Number: All applicable American Elements product codes, e.g. CU-GASE-04-GR , CU-GASE-04-P , CU-GASE-05-GR , CU-GASE-05-P

CAS #: 12018-83-6

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887

SECTION 2. HAZARDS IDENTIFICATION

Signal Word: Danger

Hazard Statements: H300+H330: Fatal if swallowed or if inhaled
H373: May cause damage to organs through prolonged or repeated exposure.
Precautionary Statements: P260: Do not breathe dust/fume/gas/mist/vapours/spray
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P284: Wear respiratory protection
P320: Specific treatment is urgent (see on this label)
P405: Store locked up
P501: Dispose of contents/container in accordance with local/regional/national/international regulations
HMIS Health Ratings (0-4):
Health: 2
Flammability: 0
Physical: 1

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Family: Semimetallic alloy
Additional Names: Copper gallium dselenide
Copper gallium selenide (CuGaSe2):
Percentage: 100 wt%
CAS #: 12018-83-6
EC #: N/A

SECTION 4. FIRST AID MEASURES

General Treatment: Seek medical attention if symptoms persist.
Special Treatment: None
Important Symptoms: None
Inhalation: Remove victim to fresh air. Supply oxygen if breathing is difficult.
Ingestion: Seek medical attention
Skin: Wash affected area with mild soap and water. Remove any contaminated clothing.
Eyes: Flush eyes with water, blinking often for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.

SECTION 5. FIREFIGHTING MEASURES

Flammability: Non-flammable
Extinguishing Media: Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Spec. Fire Fighting Procedure: Use full-face, self-contained breathing apparatus with full protective clothing to prevent contact with skin and eyes. See section 10 for decomposition products.

SECTION 6. ACCIDENTAL RELEASE MEASURES

If Material Is Released/Spilled: Wear appropriate respiratory and protective equipment specified in special protection information. Isolate spill area and provide ventilation. Vacuum up spill using a high efficiency particulate absolute (HEPA) air filter and place in a closed container for disposal. Take care not to raise dust.
Environmental Precautions: Isolate runoff to prevent environmental pollution.

SECTION 7. HANDLING AND STORAGE

Handling Conditions: Wash thoroughly after handling.
Storage Conditions: Store in a cool dry place in a tightly sealed container. Store apart from materials and conditions listed in section 10.
Work/Hygienic Maintenance: Do not use tobacco or food in work area. Wash thoroughly before eating and smoking. Do not blow dust off clothing or skin with compressed air.
Ventilation: Provide sufficient ventilation to maintain concentration at or below threshold limit.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Permissible Exposure Limits: 0.1 mg/m3 as Cu, long-term value
Threshold Limit Value: 0.2 mg/m3 as Se, long-term value
Special Equipment: None
Respiratory Protection: Dust Respirator
Protective Gloves: Rubber gloves
Eye Protection: Safety glasses or goggles
Body Protection: Protective work clothing. Wear close-toed shoes and long sleeves/pants.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Color Steel grey
Form: Powder, Granules, Pellets, Sputtering target, Custom parts
Odor: Odorless
Water Solubility: Insoluble
Boiling Point: N/A
Melting Point: N/A
Flash Point: N/A
Autoignition Temperature: N/A
Density: N/A
Molecular weight: 291.21 g/mol

SECTION 10. STABILITY AND REACTIVITY

Stability: Stable under recommended storage conditions
Reacts With: Oxidizing agents
Incompatible Conditions: None
Hazardous Decomposition Products: Metal oxide fume, Selenium dioxide, Hydrogen selenide

SECTION 11. TOXICOLOGICAL INFORMATION

Potential Health Effects:
Eyes: Causes irritating effect
Skin: Irritant to skin and mucous membranes
Ingestion: May cause irritation
Inhalation: May cause irritation
Chronic: Selenium may cause amyotropic lateral sclerosis, bronchial irritation, gastrointestinal distress, vasopharyngeal irritation, garlic odor on breath and sweat, metallic taste, pallor, irritability, excessive fatigue, loss of fingernails and hair, pulmonary edema, anemia and weight loss.
Copper compounds may be irritating to the skin, eyes and respiratory tract. They may cause metal fume fever, hemolysis of the red blood cells and injury to the liver, lungs, kidneys, and pancreas. Ingestion may also cause vomiting, gastric pain, dizziness, anemia, cramps, convulsions, shock, coma, and death.
Signs & Symptoms: N/A
Aggravated Medical Conditions: N/A
Median Lethal Dose: N/A
Carcinogen: IARC-3: Not classifiable as to carcinogenicity to humans.

SECTION 12. ECOLOGICAL INFORMATION

Aquatic Toxicity: High
Persistent Bioaccumulation Toxicity: No
Very Persistent, Very Bioaccumulative: No
Notes: Very toxic for aquatic organism.
May cause long lasting harmful effect on aquatic life.
Do not allow material to be released to the environment without proper governmental permits.
Do not allow product to reach any water sources.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Avoid transfer into the environment.

SECTION 13. DISPOSAL CONSIDERATIONS

Dispose of in accordance with local, state, national, and international regulations.

SECTION 14. TRANSPORT INFORMATION

Hazardous: Hazardous for transportation.
Hazard Class: 9 Miscellaneous hazardous substances
Packing Group: III
UN Number: UN3077
Proper Shipping Name: Environmentally hazardous substances, solid, n.o.s. (Copper gallium selenide)

SECTION 15. REGULATORY INFORMATION

Sec 302 Extremely Hazardous: No
Sec 304 Reportable Quantities: N/A
Sec 313 Toxic Chemicals: Yes

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

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About Copper Gallium Selenide

American Elements specializes in producing high purity Copper Gallium Selenide Granules and Powder with the highest possible density and smallest possible average grain sizes for use in Chemical Vapor Deposition (CVD) and Physical Vapor Deposition (PVD) processes including Thermal and Electron Beam (E-Beam) Evaporation, Low Temperature Organic Evaporation, Atomic Layer Deposition (ALD), Metallic-Organic and Chemical Vapor Deposition (MOCVD). Our standard granules are amorphous uniform pieces in sizes ranging from < 1 mm, 1-2 mm, and 3-5 mm. Materials are produced using crystallization, solid state and other ultra high purification processes such as sublimation. American Elements specializes in producing custom compositions for commercial and research applications and for new proprietary technologies. American Elements also casts any of the rare earth metals and most other advanced materials into rod, bar, or plate form, as well as other machined shapes and through other processes such as nanoparticles and in the form of solutions and organometallics.

Copper Gallium Selenide Synonyms

Copper Gallium Diselenide, CGS, CuGaSe

Chemical Identifiers

Linear Formula	CuGaSe₂
MDL Number	N/A
EC No.	N/A
Pubchem CID	44152109
IUPAC Name	copper; gallium; selenium(2-)
SMILES	[Cu+2].[Ga].[Se-2].[Se-2]
InchI Identifier	InChI=1S/Cu.Ga.2Se/q+2;;2*-2
InchI Key	IXZSSGAOIASDKD-UHFFFAOYSA-N

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Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

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