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Copper Indium Gallium Selenide Granule

CIGS

Linear Formula:

CuIn_xGa_(1-x)Se₂

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ORDER

PRODUCT	Product Code	ORDER	SAFETY DATA	TECHNICAL DATA
(2N) 99% Copper Indium Gallium Selenide Granule	CUIN-GASE-02-GR	Pricing >	SDS >	Data Sheet >
(3N) 99.9% Copper Indium Gallium Selenide Granule	CUIN-GASE-03-GR	Pricing >	SDS >	Data Sheet >
(4N) 99.99% Copper Indium Gallium Selenide Granule	CUIN-GASE-04-GR	Pricing >	SDS >	Data Sheet >
(5N) 99.999% Copper Indium Gallium Selenide Granule	CUIN-GASE-05-GR	Pricing >	SDS >	Data Sheet >

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Copper Indium Gallium Selenide Granule Properties (Theoretical)

Compound Formula	CuIn_xGa_(1-x)Se₂
Molecular Weight	Varies by composition
Appearance	Silvery
Melting Point	990-1070 °C
Boiling Point	N/A
Density	5.7 g/cm³
Solubility in H2O	N/A
Crystal Phase / Structure	tetragonal

Copper Indium Gallium Selenide Granule Health & Safety Information

Signal Word	Danger
Hazard Statements	N/A
Hazard Codes	T, N
Risk Codes	R23/25 R33 R50/53
Safety Statements	S20/21 S28 S45 S60 S61
Transport Information	N/A
GHS Pictograms	GHS09 Environment

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SAFETY DATA SHEET

Date Accessed: 12/20/2024

Date Revised: 01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Copper Indium Gallium Selenide Granule

Product Number: All applicable American Elements product codes, e.g. [field_extractor_field_product_reference]

CAS #: N/A

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887

SECTION 2. HAZARDS IDENTIFICATION

Hazard description:
T Toxic

N Dangerous for the environment
Information pertaining to particular dangers for man and environment
R 23/25 Toxic by inhalation and if swallowed.
R 33 Danger of cumulative effects.
R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH 3
FIRE 0
REACTIVITY 1
Health (acute effects) = 3
Flammability = 0
Reactivity = 1

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization:
Description: (CAS#)
Selenium - 7782-49-2
Copper - 7440-50-8
Indium - 7440-74-6
Gallium - 7440-55-3

SECTION 4. FIRST AID MEASURES

General information
Immediately remove any clothing soiled by the product. Remove breathing apparatus only after contaminated clothing has been completely removed. In case of irregular breathing or respiratory arrest provide artificial respiration.
If inhaled:
Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm. Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly. Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Do not induce vomiting; immediately call for medical help. Seek immediate medical advice.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing agents
Product is not flammable. Use fire fighting measures that suit the surrounding fire.
Special hazards caused by the material, its products of combustion or resulting gases:
In case of fire, the following can be released: Toxic metal oxide fume
Protective equipment: Wear self-contained respirator. Wear fully protective impervious suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Person-related safety precautions:
Use personal protective equipment. Keep unprotected persons away. Ensure adequate ventilation
Measures for environmental protection:
Do not allow material to be released to the environment without official permits.
Measures for cleaning/collecting:
Dispose contaminated material as waste according to item 13. Ensure adequate ventilation.
Additional information:
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7. HANDLING AND STORAGE

Handling
Information for safe handling:
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Open and handle container with care.

Information about protection against explosions and fires: The product is not flammable

Storage
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Store away from water/moisture.
Do not store together with acids.
Further information about storage conditions: Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers. Protect from humidity and water.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute. Components with limit values that require monitoring at the workplace.

Selenium and selenium compounds (as Se)
mg/m3
ACGIH TLV 0.2
Austria MAK 0.1
Belgium TWA 0.2
Denmark TWA 0.1
Finland TWA 0.1; 0.3-STEL
Germany MAK 0.1
Hungary 0.1-STEL
Ireland TLV 0.1
Japan OEL 0.1
Korea TLV 0.2
Netherlands MAC-TGG 0.1
Poland TWA 0.1; 0.3-STEL
Sweden NGV 0.1
Switzerland MAK-W 0.1
United Kingdom TWA 0.1
USA PEL 0.2
Additional information: No data
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands: Impervious gloves
Inspect gloves prior to use.
Material of gloves: The selection of suitable gloves not only depends on the material, but
also on quality. Quality will vary from manufacturer to manufacturer.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

General Information
Form:
Color: Silvery
Odor: No data available
Melting point/Melting range: No data available
Boiling point/Boiling range: No data available
Sublimation temperature / start: No data available
Flash point: N/A
Ignition temperature: No data available
Decomposition temperature: No data available
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: No data available
Upper: No data available
Vapor pressure: No data available
Density No data available
Solubility in / Miscibility with
Water: Insoluble

SECTION 10. STABILITY AND REACTIVITY

Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Materials to be avoided: Water/moisture, Acids
Dangerous reactions No dangerous reactions known
Dangerous products of decomposition: Toxic metal oxide fume

SECTION 11. TOXICOLOGICAL INFORMATION

Carcinogenicity:
NTP? No
IARC Monographs? No
OSHA Regulated? No
LD 50/LC 50: No toxicity data recorded

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxical effects:
Remark: Very toxic for fish
General notes:
Do not allow product to reach groundwater, water courses, or sewage systems, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Do not allow material to be released to the environment without official permits.
Very toxic for aquatic organisms

SECTION 13. DISPOSAL CONSIDERATIONS

Consult official regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
Recommended cleansing agent: Water, if necessary with cleansing agents.

SECTION 14. TRANSPORT INFORMATION

Not a hazardous material for transport.
No IATA regulations.

SECTION 15. REGULATORY INFORMATION

Product related hazard informations:
Hazard symbols:
T Toxic
N Dangerous for the environment
Risk phrases:
23/25 Toxic by inhalation and if swallowed.
33 Danger of cumulative effects.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety phrases:
20/21 When using do not eat, drink or smoke.
28 After contact with skin, wash immediately with plenty of water
45 In case of accident or if you feel unwell, seek medical advice immediately.
60 This material and its container must be disposed of as hazardous waste.
61 Avoid release to the environment. Refer to special instructions/Safety data sheets
National regulations
All components of this product are listed in the U.S. Environmental
Protection Agency Toxic Substances Control Act Chemical substance
Inventory.
Information about limitation of use:
For use only by technically qualified individuals.
This product contains selenium and is subject to the reporting
requirements of section 313 of the Emergency Planning and Community Right to Know Act of 1986 and 40CFR372.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

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About Copper Indium Gallium Selenide Granule

American Elements specializes in producing high purity Copper Indium Gallium Selenide (CIGS) Granules in ultra high purity for analytical standards in health and safety research and other commercial applications. Granules also exhibit the highest possible density and smallest possible average grain sizes for use in Chemical Vapor Deposition (CVD) and Physical Vapor Deposition (PVD) processes including Thermal and Electron Beam (E-Beam) Evaporation, Low Temperature Organic Evaporation, Atomic Layer Deposition (ALD), Metallic-Organic and Chemical Vapor Deposition (MOCVD). Our standard granules are amorphous uniform pieces in sizes ranging from < 1 mm, 1-2 mm, and 3-5 mm. Materials are produced using crystallization, solid state and other ultra high purification processes such as sublimation. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available.

Copper Indium Gallium Selenide Granule Synonyms

Copper indium gallium diselenide, CuInGaSe, Cu-In-Ga-Se

Chemical Identifiers

Linear Formula	CuIn_xGa_(1-x)Se₂
MDL Number	N/A
EC No.	N/A

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Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Copper

29 Cu 63.546000000 Copper

See more Copper products. Copper Bohr Model Copper (atomic symbol: Cu, atomic number: 29) is a Block D, Group 11, Period 4 element with an atomic weight of 63.546. The number of electrons in each of copper's shells is 2, 8, 18, 1 and its electron configuration is [Ar]3d¹⁰ 4s¹. The copper atom has a radius of 128 pm and a Van der Waals radius of 186 pm. Copper was first discovered by Early Man prior to 9000 BC. In its elemental form, copper has a reddish-orange metallic and lustrous appearance. Of all pure metals, only silver Elemental Copper has a higher electrical conductivity. The origin of the word copper comes from the Latin word 'cuprium' which translates as "metal of Cyprus," as the Mediterranean island of Cyprus was known as an ancient source of mined copper..

Gallium

31 Ga 69.723000000 Gallium

See more Gallium products. Gallium (atomic symbol: Ga, atomic number: 31) is a Block P, Group 13, Period 4 element with an atomic weight of 69.723.The number of electrons in each of Gallium's shells is 2, 8, 18, 3 and its electron configuration is [Ar] 3d¹⁰ 4s² 4p¹. The gallium atom has a radius of 122.1 pm and a Van der Waals radius of 187 pm. Gallium Bohr Model Gallium was predicted by Dmitri Mendeleev in 1871. It was first discovered and isolated by Lecoq de Boisbaudran in 1875. In its elemental form, gallium has a silvery appearance. Elemental Gallium Gallium is one of three elements that occur naturally as a liquid at room temperature, the other two being mercury and cesium. Gallium does not exist as a free element in nature and is sourced commercially from bauxite and sphalerite. Currently, gallium is used in semiconductor devices for microelectronics and optics. The element name originates from the Latin word 'Gallia' referring to Gaul, the old name of France.

Indium

49 In 114.818000000 Indium

See more Indium products. Indium (atomic symbol: In, atomic number: 49) is a Block P, Group 13, Period 5 element with an atomic weight of 114.818. The number of electrons in each of indium's shells is [2, 8, 18, 18, 3] and its electron configuration is [Kr] 4d¹⁰ 5s² 5p¹. The indium atom has a radius of 162.6 pm and a Van der Waals radius of 193 pm. Indium was discovered by Ferdinand Reich and Hieronymous Theodor Richter in 1863. Indium Bohr Model It is a relatively rare, extremely soft metal is a lustrous silvery gray and is both malleable and easily fusible. It has similar chemical properties to Elemental Indium gallium such as a low melting point and the ability to wet glass. Fields such as optics and microelectronics that utilize semiconductor technology have wide uses for indium, especially in the form of Indiun Tin Oxide (ITO). Thin films of Copper Indium Gallium Selenide (CIGS) are used in high-performing solar cells. Indium's name is derived from the Latin word indicum, meaning violet.

Selenium

34 Se 78.960000000 Selenium

See more Selenium products. Selenium (atomic symbol: Se, atomic number: 34) is a Block P, Group 16, Period 4 element with an atomic radius of 78.96. The number of electrons in each of Selenium's shells is 2, 8, 18, 6 and its electron configuration is [Ar] 3d¹⁰ 4s² 4p⁴. The selenium atom has a radius of 120 pm and a Van der Waals radius of 190 pm. Selenium is a non-metal with several allotropes: a black, vitreous form with an irregular crystal structure three red-colored forms with monoclinic crystal structures and a gray form with a hexagonal crystal structure, the most stable and dense form of the element. Elemental Selenium One of the most common uses for selenium is in glass production the red tint that it lends to glass neutralizes green or yellow tints from impurities in the glass materials. Selenium was discovered and first isolated by Jöns Jakob Berzelius and Johann Gottlieb Gahn in 1817. The origin of the name Selenium comes from the Greek word "Selênê," meaning moon.