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Grubbs Catalyst, 2nd Generation

CAS #:

246047-72-3

Linear Formula:

C₄₆H₆₅Cl₂N₂PRu

MDL Number:

MFCD03453237

EC No.:

N/A

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ORDER

PRODUCT	Product Code	ORDER	SAFETY DATA	TECHNICAL DATA
Benzylidene[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(tricyclohexylphosphine)rutheniumum (Grubbs Catalyst II)	RU-OMX-01-P	Pricing >	SDS >	Data Sheet >

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Grubbs Catalyst, 2nd Generation Properties (Theoretical)

Compound Formula	C₄₆H₆₅Cl₂N₂PRu
Molecular Weight	848.97
Appearance	Red to brown powder, crystals, or crystalline powder
Melting Point	143.5-148.5 °C
Boiling Point	N/A
Density	N/A
Solubility in H2O	N/A
Exact Mass	848.331 g/mol
Monoisotopic Mass	848.331 g/mol

Grubbs Catalyst, 2nd Generation Health & Safety Information

Signal Word	Warning
Hazard Statements	H228
Hazard Codes	F
Precautionary Statements	P210
RTECS Number	N/A
Transport Information	UN1325 4.1/ PG II
WGK Germany	3
MSDS / SDS	Request MSDS / SDS

About Grubbs Catalyst, 2nd Generation

(1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium (Grubbs Catalyst 2nd Generation) is one of numerous organometallic compounds manufactured by American Elements under the trade name AE Organometallics™. Organometallics are useful reagents, catalysts, and precursor materials with applications in thin film deposition, industrial chemistry, pharmaceuticals, LED manufacturing, and others. American Elements supplies organometallic compounds in most volumes including bulk quantities and also can produce materials to customer specifications. Please request a quote above for more information on pricing and lead time.

Grubbs Catalyst, 2nd Generation Synonyms

(1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium, Benzylidene[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(tricyclohexylphosphine)ruthenium, Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](benzylidene)(tricyclohexylphosphine)ruthenium(II), Grubbs Catalyst C848

Chemical Identifiers

Linear Formula	C₄₆H₆₅Cl₂N₂PRu
MDL Number	MFCD03453237
EC No.	N/A
Pubchem CID	11147261
IUPAC Name	benzylidene-[1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichlororuthenium; tricyclohexylphosphane
SMILES	CC1=CC(=C(C(=C1)C)N2CCN(C2=[Ru](=CC3=CC=CC=C3)(Cl)Cl)C4=C(C=C(C=C4C)C)C)C.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3
InchI Identifier	InChI=1S/C21H26N2.C18H33P.C7H6.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h9-12H,7-8H2,1-6H3;16-18H,1-15H2;1-6H;2*1H;/q;;;;;+2/p-2
InchI Key	FCDPQMAOJARMTG-UHFFFAOYSA-L

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RuCl(p-cymene)[(R,R)-Ts-DPEN]	RuCl[(S,S)-FsDPEN](p-cymene)	Tris(2,2′-bipyrimide)ruthenium(II) Dichloride
Dichlorotris(1,10-phenanthroline)ruthenium(II) Hydrate	Hoveyda-Grubbs Catalyst, 2nd Generation	(R,R)-Teth-TsDpen RuCl

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Chlorine

17 Cl 35.453000000 Chlorine

Chlorine is a Block P, Group 17, Period 3 element. Its electron configuration is [Ne]3s²3p⁵. The chlorine atom has a covalent radius of 102±4 pm and its Van der Waals radius is 175 pm. Chlorine Model In its elemental form, chlorine is a yellow-green gas. Chlorine is the second lightest halogen after fluorine. It has the third highest electronegativity and the highest electron affinity of all elements, making it a strong oxidizing agent. It is rarely found by itself in nature. Chlorine was discovered and first isolated by Carl Wilhelm Scheele in 1774. It was first recognized as an element by Humphry Davy in 1808.

Nitrogen

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Ruthenium

44 Ru 101.070000000 Ruthenium

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