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Hoveyda-Grubbs Catalyst, 2nd Generation

CAS #:

301224-40-8

Linear Formula:

C₃₁H₃₈Cl₂N₂ORu

MDL Number:

MFCD03701614

EC No.:

608-446-3

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PRODUCT	Product Code	ORDER	SAFETY DATA	TECHNICAL DATA
Hoveyda-Grubbs Catalyst 2st Generation, (1,3-Bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(o-isopropoxyphenylmethylene)ruthenium	RU-OMX-01-P	Pricing >	SDS >	Data Sheet >

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Hoveyda-Grubbs Catalyst, 2nd Generation Properties (Theoretical)

Compound Formula	C₃₁H₃₈Cl₂N₂ORu
Molecular Weight	626.628
Appearance	Green powder or crystalline powder
Melting Point	216-220 °C
Boiling Point	N/A
Density	N/A
Solubility in H2O	N/A
Storage Temperature	2-8 °C
Exact Mass	626.14 g/mol
Monoisotopic Mass	626.14 g/mol

Hoveyda-Grubbs Catalyst, 2nd Generation Health & Safety Information

Signal Word	Warning
Hazard Statements	H228
Hazard Codes	F
Precautionary Statements	P210
RTECS Number	N/A
Transport Information	UN1325 4.1/PG II
WGK Germany	3
GHS Pictograms	GHS02 Flame
MSDS / SDS	Request MSDS / SDS

About Hoveyda-Grubbs Catalyst, 2nd Generation

Second Generation Hoveyda-Grubbs Catalyst, or (1,3-Bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(o-isopropoxyphenylmethylene)ruthenium, is an organometallic ruthenium complex used in Ring-Closing Metathesis (RCM) to form macrocycles. American Elements supplies organometallic catalysts in most volumes including bulk quantities and also can produce materials to customer specifications. Most materials can be produced in high and ultra high purity forms (99%, 99.9%, 99.99%, 99.999%, and higher) and to many standard grades when applicable including Mil Spec (military grade), ACS, Reagent and Technical Grades, Pharmaceutical Grades, Optical, Semiconductor, and Electronics Grades. Please request a quote above for more information on pricing and lead time.

Hoveyda-Grubbs Catalyst, 2nd Generation Synonyms

HG-II, Grubbs Catalyst C627, Second Generation Hoveyda-Grubbs Catalyst, (1,3-Bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(o-isopropoxyphenylmethylene)ruthenium, Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](2-isopropoxyphenylmethylene)ruthenium(II), 1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI) chloride, Ruthenium, [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy-κO)phenyl]methylene-κC]-, (SP-5-41)-

Chemical Identifiers

Linear Formula	C₃₁H₃₈Cl₂N₂ORu
MDL Number	MFCD03701614
EC No.	608-446-3
Pubchem CID	11763533
IUPAC Name	[1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-[(2-propan-2-yloxyphenyl)methylidene]ruthenium
SMILES	CC1=CC(=C(C(=C1)C)N2CCN(C2=[Ru](=CC3=CC=CC=C3OC(C)C)(Cl)Cl)C4=C(C=C(C=C4C)C)C)C
InchI Identifier	InChI=1S/C21H26N2.C10H12O.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-8(2)11-10-7-5-4-6-9(10)3;;;/h9-12H,7-8H2,1-6H3;3-8H,1-2H3;2*1H;/q;;;;+2/p-2
InchI Key	ZRPFJAPZDXQHSM-UHFFFAOYSA-L

Customers For Hoveyda-Grubbs Catalyst, 2nd Generation Have Also Viewed

cis-Dichlorobis(2,2′-bipyridine)ruthenium(II) Hydrate	RuCl(p-cymene)[(R,R)-Ts-DPEN]	RuCl[(S,S)-FsDPEN](p-cymene)
RuCl(p-cymene)[(S,S)-Ts-DPEN]	RuCl[(R,R)-FsDPEN](p-cymene)	Tris(2,2′-bipyrimide)ruthenium(II) Dichloride
Dichlorotris(1,10-phenanthroline)ruthenium(II) Hydrate	Grubbs Catalyst, 2nd Generation	(R,R)-Teth-TsDpen RuCl

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Chlorine

17 Cl 35.453000000 Chlorine

Chlorine is a Block P, Group 17, Period 3 element. Its electron configuration is [Ne]3s²3p⁵. The chlorine atom has a covalent radius of 102±4 pm and its Van der Waals radius is 175 pm. Chlorine Model In its elemental form, chlorine is a yellow-green gas. Chlorine is the second lightest halogen after fluorine. It has the third highest electronegativity and the highest electron affinity of all elements, making it a strong oxidizing agent. It is rarely found by itself in nature. Chlorine was discovered and first isolated by Carl Wilhelm Scheele in 1774. It was first recognized as an element by Humphry Davy in 1808.

Nitrogen

7 N 14.006700000 Nitrogen

See more Nitrogen products. Nitrogen is a Block P, Group 15, Period 2 element. Its electron configuration is [He]2s²2p³. Nitrogen is an odorless, tasteless, colorless and mostly inert gas. It is the seventh most abundant element in the universe and it constitutes 78.09% (by volume) of Earth's atmosphere. Nitrogen was discovered by Daniel Rutherford in 1772.

Ruthenium

44 Ru 101.070000000 Ruthenium

See more Ruthenium products. Ruthenium (atomic symbol: Ru, atomic number: 44) is a Block D, Group 8, Period 5 element with an atomic weight of 101.07. Ruthenium Bohr Model The number of electrons in each of ruthenium's shells is [2, 8, 18, 15, 1] and its electron configuration is [Kr] 4d⁷ 5s¹. The ruthenium atom has a radius of 134 pm and a Van der Waals radius of 207 pm. Ruthenium was discovered by Jędrzej Śniadecki in 1807. It was first recognized as a distinct element by Karl Ernst Claus in 1844. Elemental Ruthenium In its elemental form, ruthenium has a silvery white metallic appearance. Ruthenium is a rare transition metal belonging to the platinum group of metals. It is found in pentlandite, pyroxenite, and platinum group metal ores. The name Ruthenium originates from the Latin word "Ruthenia," meaning Russia.