Manganese Nitride Mn3N2

SECTION 1. IDENTIFICATION

Product Name: Manganese Nitride Mn3N2

Product Number: All applicable American Elements product codes, e.g. MN2-N-02 , MN2-N-03 , MN2-N-04 , MN2-N-05

CAS #: 12646-17-2

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887

SECTION 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H332 Harmful if inhaled.
Skin Irrit. 2
H315 Causes skin irritation.
Eye Irrit. 2
H319 Causes serious eye irritation.
STOT SE 3 H335 May cause respiratory irritation.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Xn; Harmful
R20/22: Harmful by inhalation and if swallowed.
Xi; Irritant
R36/37/38: Irritating to eyes, respiratory system and skin.
Information concerning particular hazards for human and environment:
Not applicable
Other hazards that do not result in classification
No information known.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation.
Hazard pictograms

GHS07
Signal word
Warning
Hazard statements
H302 Harmful if swallowed.
H332 Harmful if inhaled.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statements
P261
Avoid breathing dust/fume/gas/mist/vapours/spray.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P304+P340
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P405
Store locked up.
P501
Dispose of contents/container in accordance with local/regional/national/international regulations.
2.3 Other hazards
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances
CAS# Designation:
12646-17-2
Manganese nitride
Formula: Mn3N2

SECTION 4. FIRST AID MEASURES

4.1 Description of first aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
Seek immediate medical advice.
After skin contact
Instantly wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult doctor.
After swallowing
Seek medical treatment.
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5. FIREFIGHTING MEASURES

5.1 Extinguishing media
Suitable extinguishing agents
CO2, sand, extinguishing powder. Do not use water.
5.2 Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Nitrogen oxides (NOx)
Toxic metal oxide smoke
5.3 Advice for firefighters
Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
6.2 Environmental precautions:
Do not allow material to be released to the environment without proper governmental permits.
6.3 Methods and material for containment and cleaning up:
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards:
No special measures required.
6.4 Reference to other sections
See Section 7 for information on safe handling
See section 8 for information on personal protection equipment.
See Section 13 for information on disposal.

SECTION 7. HANDLING AND STORAGE

7.1 Precautions for safe handling
Keep containers tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation/exhaustion at the workplace.
Information about protection against explosions and fires:
No information known.
7.2 Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and containers:
No special requirements.
Information about storage in one common storage facility:
Store away from oxidising agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
7.3 Specific end use(s)
No further relevant information available.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures should be adhered to in handling the chemicals.
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use breathing protection with high concentrations.
Protection of hands:
Check protective gloves prior to each use for their proper condition.
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
Material of gloves
Impervious gloves
Eye protection:
Safety glasses
Face protection
Body protection:
Protective work clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties
General Information
Appearance:
Form: Powder
Colour: Dark
Smell: Odourless
Odour threshold: Not determined.
pH-value: Not applicable
Change in condition
Melting point/Melting range: >1800 °C
Boiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Flash point: Not applicable
Inflammability (solid, gaseous)
Product is not inflammable.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Self-inflammability: Not determined.
Danger of explosion: Product is not explosive.
Critical values for explosion:
Lower: Not determined
Upper: Not determined
Steam pressure: Not applicable.
Density at 20 °C
5.9 g/cm³
Relative density
Not determined.
Vapour density
Not applicable.
Evaporation rate
Not applicable.
Solubility in / Miscibility with Water: Insoluble
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
9.2 Other information
No further relevant information available.

SECTION 10. STABILITY AND REACTIVITY

10.1 Reactivity
No information known.
10.2 Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
10.3 Possibility of hazardous reactions
Contact with acids releases flammable gases
10.4 Conditions to avoid
No further relevant information available.
10.5 Incompatible materials:
Oxidising agents
10.6 Hazardous decomposition products:
Nitrogen oxides (NOx)
Metal oxide

SECTION 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects
Acute toxicity:
Harmful if inhaled.
Harmful if swallowed.
LD/LC50 values that are relevant for classification:
No data
Skin irritation or corrosion:
Causes skin irritation.
Eye irritation or corrosion:
Causes serious eye irritation.
Sensitization:
No sensitizing effect known.
Germ cell mutagenicity:
No effects known.
Carcinogenicity:
EPA-D: Not classifiable as to human carcinogenicity: inadequate human and animal evidence of carcinogenicity or no data are available.
IARC-3: Not classifiable as to carcinogenicity to humans.
ACGIH A4: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in terms of its carcinogenicity in humans and/or animals.
Reproductive toxicity:
No effects known.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
May cause respiratory irritation.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
No effects known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.

SECTION 12. ECOLOGICAL INFORMATION

12.1 Toxicity
Aquatic toxicity:
No further relevant information available.
12.2 Persistence and degradability
No further relevant information available.
12.3 Bioaccumulative potential
No further relevant information available.
12.4 Mobility in soil
No further relevant information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities to reach ground water, water course or sewage system.
Avoid transfer into the environment.
12.5 Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
12.6 Other adverse effects
No further relevant information available.

SECTION 13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods
Recommendation
Hand over to disposers of hazardous waste.
Must be specially treated under adherence to official regulations.
Consult state, local or national regulations for proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.

SECTION 14. TRANSPORT INFORMATION

UN-Number
ADR, IMDG, IATA
None
14.2 UN proper shipping name
ADR, IMDG, IATA
None
14.3 Transport hazard class(es)
ADR, IMDG, IATA
Class
None
Packing group
ADR, IMDG, IATA
None
14.5 Environmental hazards:
Not applicable.
14.6 Special precautions for user
Not applicable.
14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC
Code
Not applicable.
Transport/Additional information:
Not dangerous according to the above specifications.

SECTION 15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Australian Inventory of Chemical Substances
Substance is not listed.
Standard for the Uniform Scheduling of Drugs and Poisons
Substance is not listed.
National regulations
Information about limitation of use:
Employment restrictions concerning young persons must be observed.
For use only by technically qualified individuals.
Water hazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Other regulations, limitations and prohibitive regulations
ELINCS (European List of Notified Chemical Substances)
Substance is not listed.
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
15.2 Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.