Manganese(II) Hypophosphite Monohydrate

SECTION 1. IDENTIFICATION

Product Name: Manganese(II) Hypophosphite Monohydrate

Product Number: All applicable American Elements product codes, e.g. MN-HP-02-P.1HYD , MN-HP-03-P.1HYD , MN-HP-04-P.1HYD , MN-HP-05-P.1HYD

CAS #: 7783-16-6

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS08 Health hazard
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
Hazards not otherwise classified
No data available
GHS label elements
GHS label elements, including precautionary statements
Hazard pictograms
Substances
CAS No. / Substance Name:
7783-16-6 Manganese(II) hypophosphite monohydrate

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

GHS08
Signal word
Warning
Hazard statements
H373 May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P314 Get medical advice/attention if you feel unwell.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D2A - Very toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 2
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A

SECTION 4. FIRST AID MEASURES

Description of first aid measures
If inhaled:
Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No data available
Indication of any immediate medical attention and special treatment needed
No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Phosphorus oxides
Metal oxide fume
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. K
eep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:
Do not allow material to be released to the
environment without official permits.
Methods and materials for containment and cleanup:
Dispose of contaminated material as waste according to section 13.
Prevention of secondary hazards:
No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information
on personal protection equipment.
See Section 13 for disposal information.

SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in
tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires:
The product is not flammable
Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Specific end use(s)
No data available

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
Manganese, elemental & inorganic compounds (as Mn)
mg/m3
ACGIH TLV 0.2
Austria MAK 5
Belgium TWA 5
Denmark TWA 2.5
Finland TWA 0.5
Hungary TWA 0.3; 0.6-STEL
Germany MAK 0.55
Japan OEL 0.3 (respirable dust)
Korea TLV 0.2
Netherlands MAC-TGG 1; 3-MAC-K
Norway TWA 2.5
Poland TWA 0.3; 5-MAC
Russia 0.2-STEL (fume)
Sweden NGV 1; 2.5-TGV (respirable dust)
2.5; 5-TGV (total dust)
United Kingdom TWA 5
USA PEL 5-Ceiling
Additional information:
No data
Exposure controls
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
Suitability of gloves should be determined both by material and quality, the latter of which may vary by manufacturer.
Penetration time of glove material (in minutes)
No data available
Eye protection:
Safety glasses
Body protection:
Protective work clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form:
Crystalline
Color:
Colorless
Odor:
No data available
Odor threshold:
No data available.
H-value:
N/A
Melting point/Melting range:
No data available
Boiling point/Boiling range:
No data available
Sublimation temperature / start:
No data available
Flash point:
N/A
Flammability (solid, gas)
No data available.
Ignition temperature:
No data available
Decomposition temperature:
No data available
Autoignition:
No data available.
Danger of explosion:
Product does not present an explosion hazard.
Explosion limits:
Lower:
No data available
Upper:
No data available
Vapor pressure:
N/A
Density:
No data available
Relative density
No data available.
Vapor density
N/A
Evaporation rate
N/A
Solubility in / Miscibility with
Water:
No data available
Partition coefficient (n-octanol/water):
No data available.
Viscosity:
Dynamic:
N/A
Kinematic:
N/A
Other information
No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and
stored according to specifications.
Possibility of hazardous reactions
No dangerous reactions known
Conditions to avoid
No data available
Incompatible materials:
Oxidizing agents
Hazardous decomposition products:
Phosphorus oxides (e.g. P2O5)
Metal oxide fume

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
No effects known.
LD/LC50 values that are relevant for classification:
No data
Skin irritation or corrosion:
May cause irritation
Eye irritation or corrosion:
May cause irritation
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
No effects known.
Carcinogenicity:
EPA-D: Not classifiable as to human carcinogenicity: inadequate human and animal evidence of carcinogenicity or no data are available.
Reproductive toxicity:
No effects known.
Specific target organ system toxicity - repeated exposure:
May cause damage to organs through prolonged or repeated exposure.
Specific target organ system toxicity - single exposure:
No effects known.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
Chronic exposure to manganese may cause impairment to the central nervous system. Symptoms include sluggishness, sleepiness, muscle weakness, loss of
facial muscle control, edema, emotional disturbances, spastic gait and falling.
Inorganic phosphorus compounds may cause irritation and hemorrhages in the stomach as well as liver and kidney damage. Bone structure may be attacked, especially the jaw and teeth.
Subacute to chronic toxicity:
No effects known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known

SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Ecotoxical effects:
Remark:
Toxic for aquatic organisms
Additional ecological information:
Do not allow product to reach groundwater, water courses, or sewage systems.
Toxic for aquatic organisms
Do not allow material to be released to the environment without official permits.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic to aquatic life.
May cause long lasting harmful effects to aquatic life.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A
Other adverse effects
No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Consult official regulations to ensure proper disposal
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.

SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA
UN3077
UN proper shipping name
DOT
Environmentally hazardous substances,
solid, n.o.s. (Manganese(II) hypophosphite
monohydrate)
IMDG, IATA
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(Manganese(II) hypophosphite monohydrate)
Transport hazard class(es)
DOT, IMDG
Class
9 Miscellaneous dangerous subs
tances and articles.
Label
9
Class
9 (M7) Miscellaneous dangerous
substances and articles
Label
9
IATA
Class
9 Miscellaneous dangerous subs
tances and articles.
Label
9
Packing group
DOT, IMDG, IATA
III
Environmental hazards:
Special marking (ADR):
Symbol (fish and tree)
Special marking (IATA):
Symbol (fish and tree)
Special precautions for user
Warning: Miscellaneous dangerous substances and articles
EMS Number:
F-A,S-F
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N/A
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
UN "Model Regulation":
UN3077, Environmentally hazardous s
ubstances, solid, n.o.s. (Manganese(II) hypophosphite monohydrate), 9, II

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS GHS label elements, including precautionary statements
Hazard pictograms
GHS08
Signal word
Warning
Hazard statements
H373 May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P314 Get medical advice/attention if you feel unwell.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on t
he Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
7783-16-6 Manganese(II) hypophosphite monohydrate
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
This product contains manganese and is subject to the reporting requirements of section 313 of the Emergency Planning and Community Right to Know Act of 1986 and 40CFR372.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.