Sodium Selenite Pentahydrate

SECTION 1. IDENTIFICATION

Product Name: Sodium Selenite Pentahydrate

Product Number: All applicable American Elements product codes, e.g. NA-SEIT-02-C.5HYD , NA-SEIT-03-C.5HYD , NA-SEIT-04-C.5HYD , NA-SEIT-05-C.5HYD

CAS #: 26970-82-1

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Acute toxicity, Oral(Category 2), H300
Acute toxicity, Inhalation(Category 3), H331
Skin sensitisation(Category 1), H317
Acute aquatic toxicity(Category 2), H401
Chronic aquatic toxicity(Category 2), H411

GHS Label elements, including precautionary statements
Pictogram

Signal word
Danger
Hazard statement(s)
H300
Fatal if swallowed.
H317
May cause an allergic skin reaction.
H331
Toxic if inhaled.
H411
Toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P261
Avoid breathing dust/ fume/ gas/ mist/ Vapors/ spray.
P264
Wash skin thoroughly after handling.
P270
Do not eat, drink or smoke when using this product.
P271
Use only outdoors or in a well-ventilated area.
P272
Contaminated work clothing should not be allowed out of the workplace.
P273
Avoid release to the environment.
P280
Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P310 + P330
IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. Rinse mouth.
P302 + P352
IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 + P311
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/ physician.
P333 + P313
If skin irritation or rash occurs: Get medical advice/ attention.
P363
Wash contaminated clothing before reuse.
P391
Collect spillage.
P403 + P233
Store in a well-ventilated place. Keep container tightly closed.
P405
Store locked up.
P501
Dispose of contents/ container to an approved waste disposal plant.
Hazards not otherwise classified (HNOC) or not covered by GHS
Contact with acids liberates toxic gas.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
Formula: Na2O3Se 5H2O
Molecular weight: 263.01 g/mol
CAS-No.: 26970-82-1
EC-No.: 233-267-9
Index-No.: 034-003-00-3

SECTION 4. FIRST AID MEASURES

Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person.
Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11
Indication of any immediate medical attention and special treatment needed
No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing media
Dry powder
Special hazards arising from the substance or mixture
Sodium oxides, Selenium/selenium oxides
Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
Further information
No data available

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear respiratory protection. Avoid dust formation.
Avoid breathing Vapors, mist or gas. Ensure adequate ventilation.
Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Do not flush with water. Keep in suitable, closed containers for disposal.
Reference to other sections
For disposal see section 13.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Further processing of solid materials may result in the formation of combustible dusts. The potential for combustible dust formation should be taken into consideration before additional processing occurs.
Provide appropriate exhaust ventilation at places where dust is formed.
For precautions see section 2.
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Never allow product to get in contact with water during storage. Do not store near acids.
hygroscopic
Storage class (TRGS 510): Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
Specific end use(s)
Apart from the uses mentioned in section 1 no other specific uses are stipulated

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal
technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance
Form: crystalline
Color: white
Odor
No data available
Odor Threshold
No data available
pH
9 at 50 g/l at 20 °C (68 °F)
Melting point/freezing point
No data available
Initial boiling point and boiling range
No data available
Flash point
N/A
Evaporation rate
No data available
Flammability (solid, gas)
No data available
Upper/lower flammability or explosive limits
No data available
Vapor pressure
No data available
Vapor density
No data available
Relative density
No data available
Water solubility
soluble
Partition coefficient: n-octanol/water
No data available
Auto-ignition temperature
No data available
Decomposition temperature
> 300 °C (> 572 °F)-
Viscosity
No data available
Explosive properties
No data available
Oxidizing properties
No data available
Other safety information
No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
No data available
Conditions to avoid
No data available
Incompatible materials
Strong oxidizing agents, Strong acids
Hazardous decomposition products
Other decomposition products-No data available
In the event of fire: see section 5

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity
LD50 Oral-Rat-7 mg/kg
Dermal: No data available
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
Germ cell mutagenicity
Mouse
mammary gland
DNA damage
Mouse
mammary gland
DNA inhibition
Carcinogenicity
This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification.
IARC:
3-Group 3: Not classifiable as to its carcinogenicity to humans(Sodium selenite pentahydrate)
ACGIH:
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by ACGIH.
NTP:
No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA:
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
No data available
Reproductive toxicity-Mouse-Subcutaneous
Effects on Fertility: Abortion.
Reproductive toxicity-Mouse-Subcutaneous
Effects on Newborn: Live birth index (# fetuses per litter; measured after birth).
No data available
Developmental Toxicity-Mouse-Oral
Effects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus). Specific Developmental Abnormalities: Musculoskeletal system.
Specific target organ toxicity -single exposure
No data available
Specific target organ toxicity -repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: VS7420000
Nausea, Dizziness, Headache, anemia, Salivation, Tremors, Alopecia., Vomiting, Dermatitis, To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Stomach-Irregularities-Based on Human Evidence
Stomach-Irregularities-Based on Human Evidence

SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Toxicity to fish
LC50-Cyprinodon variegatus (sheepshead minnow)-4.5 -12.0 mg/l-96.0 h
Toxicity to daphnia and other aquatic invertebrates
EC50-Daphnia magna (Water flea)-7.9 mg/l-48 h
Toxicity to algae
EC50-Pseudokirchneriella subcapitata (green algae)-3.2 -10.0 mg/l-72 h
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.
Toxic to aquatic life with long lasting effects.

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contact a licensed professional waste disposal service to dispose of this material.
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.

SECTION 14. TRANSPORT INFORMATION

DOT (US)
UN number: 2630
Class: 6.1
Packing group: I
Proper shipping name: Selenites(Sodium selenite pentahydrate)
Reportable Quantity(RQ):
Poison Inhalation Hazard: No
IMDG
UN number: 2630
Class: 6.1
Packing group: I
EMS-No: F-A, S-A
Proper shipping name: SELENITES(Sodium selenite pentahydrate)
Marine pollutant: yes
IATA
UN number: 2630
Class: 6.1
Packing group: I
Proper shipping name: Selenites(Sodium selenite pentahydrate)

SECTION 15. REGULATORY INFORMATION

SARA 302 Components
The following components are subject to reporting levels established by SARA Title III, Section 302:
Sodium selenite pentahydrate
CAS-No.
26970-82-1
Revision Date
2007-07-01
SARA 313 Components
The following components are subject to reporting levels established by SARA Title III, Section 313:
Sodium selenite pentahydrate
CAS-No.
26970-82-1
Revision Date
2007-07-01
SARA 311/312 Hazards
Acute Health Hazard, Chronic Health Hazard
Massachusetts Right To Know Components
Sodium selenite pentahydrate
CAS-No.
26970-82-1
Revision Date
2007-07-01
Pennsylvania Right To Know Components
Sodium selenite pentahydrate
CAS-No.
26970-82-1
Revision Date
2007-07-01
New Jersey Right To Know Components
Sodium selenite pentahydrate
CAS-No.
26970-82-1
Revision Date
2007-07-01
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.