Titanium Phosphide

SECTION 1. IDENTIFICATION

Product Name: Titanium Phosphide

Product Number: All applicable American Elements product codes, e.g. TI-P-02 , TI-P-03 , TI-P-04 , TI-P-05

CAS #: 12037-65-9

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887

SECTION 2. HAZARDS IDENTIFICATION

Signal Word: Warning

Hazard Statements: H228: Flammable solid
H302+H312+H332: Harmful if swallowed, in contact with skin or if inhaled
H315: Causes skin irritation
H319: Causes serious eye irritation
H335: May cause respiratory irritation
Precautionary Statements: P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking
P240: Ground/bond container and receiving equipment
P241: Use explosion-proof electrical/ventilating/lighting/equipment
P261: Avoid breathing dust/fume/gas/mist/vapors/spray
P280: Wear protective gloves/protective clothing/eye protection/face protection
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P302+P352: IF ON SKIN: Wash with soap and water
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing
P370+P378: In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction
HMIS Health Ratings (0-4):
Health: 1
Flammability: 2
Physical: 2

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Family: Inorganic Compound
Additional Names: None
Titanium Phosphide (TiP)
Percentage: 100 wt%
CAS #: 12037-65-9
EC #: 243-862-6

SECTION 4. FIRST AID MEASURES

General Treatment: Seek medical attention if symptoms persist.
Special Treatment: None
Important Symptoms: N/A
Inhalation: Remove victim to fresh air. Supply oxygen if breathing is difficult. Seek medical attention.
Ingestion: Rinse mouth with water. Do not induce vomiting. Seek medical attention.
Skin: Wash affected area with mild soap and water. Remove any contaminated clothing. Seek medical attention.
Eyes: Flush eyes with water, blinking often for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Seek medical attention.

SECTION 5. FIREFIGHTING MEASURES

Flammability: Flammable
Extinguishing Media: Do not use water for metal fires. Use class D or other metal extinguishing agent.
Spec. Fire Fighting Procedure: Use full-face, self-contained breathing apparatus with full protective clothing to prevent contact with skin and eyes. See section 10 for decomposition products.

SECTION 6. ACCIDENTAL RELEASE MEASURES

If Material Is Released/Spilled: Wear appropriate respiratory and protective equipment specified in special protection information. Isolate spill area and provide ventilation. Vacuum up spill using a high efficiency particulate absolute (HEPA) air filter and place in a closed container for disposal. Take care not to raise dust.
Environmental Precautions: Isolate runoff to prevent environmental pollution.

SECTION 7. HANDLING AND STORAGE

Handling Conditions: Wash thoroughly after handling.
Storage Conditions: Store in a cool dry place in a tightly sealed container. Store apart from materials and conditions listed in section 10.
Work/Hygienic Maintenance: Do not use tobacco or food in work area. Wash thoroughly before eating and smoking. Do not blow dust off clothing or skin with compressed air.
Ventilation: Provide sufficient ventilation to maintain concentration at or below threshold limit.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Permissible Exposure Limits: N/A
Threshold Limit Value: N/A
Special Equipment: None
Respiratory Protection: Use a recommended dust respirator or mask. Only use equipment tested and approved under appropriate government standards.
Protective Gloves: Nitrile or rubber gloves
Eye Protection: Safety glasses or goggles
Body Protection: Protective work clothing. Wear close-toed shoes and long sleeves/pants.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Color Metallic grey
Form: Powder, Granules, Pellets, Sputtering target, Custom parts
Odor: N/A
Water Solubility: Insoluble
Boiling Point: N/A
Melting Point: 1900 °C
Flash Point: N/A
Autoignition Temperature: N/A
Density: 3.95 gm/ml
Molecular weight: 78.84 g/mol

SECTION 10. STABILITY AND REACTIVITY

Stability: Stable under recommended storage conditions
Reacts With: Oxidizing agents, Water, Steam moisture, Acids and Acid fumes
Incompatible Conditions: Heat, Flames, Sparks and other Ignition sources
Hazardous Decomposition Products: Titanium oxides, Phosphorous oxides and Hydrogen Phosphide (Phosphine)

SECTION 11. TOXICOLOGICAL INFORMATION

Potential Health Effects:
Eyes: Causes serious irritation
Skin: Harmful in contact
Ingestion: Harmful if swallowed
Inhalation: Harmful if inhaled
Chronic: N/A
Signs & Symptoms: N/A
Aggravated Medical Conditions: N/A
Median Lethal Dose: N/A
Carcinogen: N/A

SECTION 12. ECOLOGICAL INFORMATION

Aquatic Toxicity: N/A
Persistent Bioaccumulation Toxicity: N/A
Very Persistent, Very Bioaccumulative: N/A
Notes: N/A

SECTION 13. DISPOSAL CONSIDERATIONS

Dispose of in accordance with local, state, national, and international regulations.

SECTION 14. TRANSPORT INFORMATION

Hazardous: Hazardous as powder only
Hazard Class: 4.1 Flammable Solids
Packing Group: III
UN Number: UN 3178
Proper Shipping Name: Flammable solid, inorganic, n.o.s. (Titanium Phosphide)

SECTION 15. REGULATORY INFORMATION

Sec 302 Extremely Hazardous: No
Sec 304 Reportable Quantities: N/A
Sec 313 Toxic Chemicals: N/A

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.