Tungsten(VI) Isopropoxide

SECTION 1. IDENTIFICATION

Product Name: Tungsten(VI) Isopropoxide

Product Number: All applicable American Elements product codes, e.g. W-IP-01-SOL

CAS #: 52321-90-1

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887

SECTION 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 2
H225 Highly flammable liquid and vapour.
GHS05 corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
GHS07
STOT SE 3
H336 May cause drowsiness or dizziness.
Other hazards that do not result in classification
No information known.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
Hazard pictograms

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GHS02 GHS05 GHS07
Signal word
Danger
Hazard-determining components of labelling:
2-Propanol
Tungsten(VI) isopropoxide
Hazard statements
H225 Highly flammable liquid and vapour.
H314 Causes severe skin burns and eye damage.
H336 May cause drowsiness or dizziness.
Precautionary statements
P210
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P260
Do not breathe dust/fume/gas/mist/vapours/spray.
P261
Avoid breathing dust/fume/gas/mist/vapours/spray.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P304+P340
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P405
Store locked up.
P501
Dispose of contents/container in accordance with local/regional/national/international regulations.
2.3 Other hazards
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

CAS: 67-63-0
2-Propanol
EINECS: 200-661-7

CAS: 52321-90-1
Tungsten(VI) isopropoxide

SECTION 4. FIRST AID MEASURES

4.1 Description of first aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
Seek immediate medical advice.
After skin contact
Instantly wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult doctor.
After swallowing
Seek medical treatment.
4.2 Most important symptoms and effects, both acute and delayed
Causes severe skin burns.
May cause respiratory irritation.
May cause drowsiness or dizziness.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5. FIREFIGHTING MEASURES

5.1 Extinguishing media
Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
5.2 Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Carbon monoxide and carbon dioxide
Tungsten oxides
5.3 Advice for firefighters
Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
6.2 Environmental precautions:
Do not allow product to reach sewage system or water bodies.
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Prevention of secondary hazards:
Keep away from ignition sources.
6.4 Reference to other sections
See Section 7 for information on safe handling
See section 8 for information on personal protection equipment.
See Section 13 for information on disposal.

SECTION 7. HANDLING AND STORAGE

7.1 Precautions for safe handling
Handle under dry protective gas.
Keep containers tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation/exhaustion at the workplace.
Information about protection against explosions and fires:
Protect against electrostatic charges.
Fumes can combine with air to form an explosive mixture.
Keep ignition sources away - Do not smoke.
7.2 Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and containers:
Store in cool location.
Information about storage in one common storage facility:
Store away from water.
Store away from oxidising agents.
Further information about storage conditions:
Store under dry inert gas.
This product is moisture sensitive.
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Protect from humidity and keep away from water.
7.3 Specific end use(s)
No further relevant information available.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
8.1 Control parameters
Components with critical values that require monitoring at the workplace:
67-63-0 2-Propanol (95.0%)
WEL () Short-term value: 1250 mg/m³, 500 ppm
Long-term value: 999 mg/m³, 400 ppm
Additional information:
No data
8.2 Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures should be adhered to in handling the chemicals.
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Do not inhale dust / smoke / mist.
Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use breathing protection with high concentrations.
Recommended filter device for short term use:
Use a respirator with multi-purpose combination (US) or type ABEK (EN 14387) as a backup to engineering controls. Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only use equipment tested and approved under appropriate government standards such as NIOSH (USA) or CEN (EU).
Protection of hands:
Check protective gloves prior to each use for their proper condition.
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
Material of gloves
Nitrile rubber, NBR
Penetration time of glove material (in minutes)
480
Glove thickness
0.4 mm
Eye protection:
Safety glasses
Face protection
Body protection:
Protective work clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Smell: Not determined
Odour threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range: -90 °C
Boiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Flash point: 12 °C (Isopropanol)
Inflammability (solid, gaseous)
Not determined.
Ignition temperature: 455 °C
Decomposition temperature: Not determined
Self-inflammability: Product is not selfigniting.
Danger of explosion: Product is not explosive. However, formation of explosive air/steam
mixtures is possible.
Critical values for explosion:
Lower: 2 Vol %
Upper: 12 Vol %
Steam pressure at 20 °C: 48 hPa
Density at 20 °C
0.785 g/cm³
Relative density
Not determined.
Vapour density
Not determined.
Evaporation rate
Not determined.
Solubility in / Miscibility with Water: Not miscible or difficult to mix
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not determined.
kinematic: Not determined.
Solvent content:
Organic solvents: 95.0 %
9.2 Other information
No further relevant information available.

SECTION 10. STABILITY AND REACTIVITY

10.1 Reactivity
No information known.
10.2 Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
10.3 Possibility of hazardous reactions
Reacts with strong oxidising agents
10.4 Conditions to avoid
No further relevant information available.
10.5 Incompatible materials:
Water/moisture
Oxidising agents
10.6 Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Tungsten oxides

SECTION 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects
Acute toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for components in this product.
LD/LC50 values that are relevant for classification:
67-63-0 2-Propanol
Oral LD50
5045 mg/kg (rat)
Dermal LD50
12800 mg/kg (rabbit)
Inhalative LC50/8H 12560 ppm/8H (rat)
Skin irritation or corrosion:
Causes skin irritation.
Eye irritation or corrosion:
Causes serious eye irritation.
Sensitization:
No sensitizing effect known.
Germ cell mutagenicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains mutation data for components in this product.
Carcinogenicity:
IARC-3: Not classifiable as to carcinogenicity to humans.
ACGIH A4: Not classifiable as a human carcinogen: Inadequate data on which to classify
the agent in terms of its carcinogenicity in humans and/or animals.
Reproductive toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains reproductive data for components in this product.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
May cause respiratory irritation.
May cause drowsiness or dizziness.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for this substance.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
The product shows the following dangers according to the calculation
method of the General EC Classification Guidelines for Preparations as issued in the
latest version:
Irritant

SECTION 12. ECOLOGICAL INFORMATION

12.1 Toxicity
Aquatic toxicity:
No further relevant information available.
12.2 Persistence and degradability
No further relevant information available.
12.3 Bioaccumulative potential
No further relevant information available.
12.4 Mobility in soil
No further relevant information available.
Additional ecological information:
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities to reach ground water, water course or sewage system.
Avoid transfer into the environment.
12.5 Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
12.6 Other adverse effects
No further relevant information available.

SECTION 13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods
Recommendation
Hand over to disposers of hazardous waste.
Must be specially treated under adherence to official regulations.
Consult state, local or national regulations for proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.

SECTION 14. TRANSPORT INFORMATION

UN-Number
ADR, IMDG, IATA
UN1219
14.2 UN proper shipping name
ADR
1219 ISOPROPANOL (ISOPROPYL ALCOHOL)
IMDG, IATA
ISOPROPANOL (ISOPROPYL ALCOHOL)
14.3 Transport hazard class(es)
ADR
Class
3 (F1) Flammable liquids.
Label
3
IMDG, IATA
Class
3 Flammable liquids.
Label
3
Packing group
ADR, IMDG, IATA
II
14.5 Environmental hazards:
Marine pollutant:
No
14.6 Special precautions for user
Warning: Flammable liquids.
Kemler Number: 33
EMS Number: F-E,S-D
14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC
Code
Not applicable.
Transport/Additional information:
ADR
Excepted quantities (EQ):
E2
Limited quantities (LQ)
1L
Transport category
2
Tunnel restriction code
D/E
UN "Model Regulation":
UN1219, ISOPROPANOL (ISOPROPYL ALCOHOL), 3, II

SECTION 15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Australian Inventory of Chemical Substances
67-63-0 2-Propanol
Standard for the Uniform Scheduling of Medicines and Poisons
None of the ingredients is listed.
National regulations
Information about limitation of use:
For use only by technically qualified individuals.
Employment restrictions concerning young persons must be observed.
Classification according to VbF:
A I
Technical instructions (air):
Class Share in %
NK
95.0
Water hazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Other regulations, limitations and prohibitive regulations
ELINCS (European List of Notified Chemical Substances)
None of the ingredients is listed.
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
None of the ingredients are listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
None of the ingredients is listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
None of the ingredients is listed.
15.2 Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
Employers should use this information only as a supplement to other information gathered by them, and should make independent judgement of suitability of this information to ensure proper use and protect the health and safety of employees. This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user.
Relevant phrases
H225 Highly flammable liquid and vapour.
H314 Causes severe skin burns and eye damage.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.